邻苯甲酰羟胺:过渡金属催化C-N键形成反应的多功能亲电胺化试剂

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2022-12-18 DOI:10.1007/s41061-022-00414-5
Sachin Balaso Mohite, Milan Bera, Vishal Kumar, Rajshekhar Karpoormath, Shaik Baji Baba, Arjun S. Kumbhar
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引用次数: 4

摘要

由于含氮化合物普遍存在于天然产物和重要的药物制剂中,化学家们一直在积极寻找高效和选择性的方法,以方便地构建碳-氮键。在过去的十年中,过渡金属催化的C-N键通过亲电胺化反应构建已成为合成各种有机分子和药物的一种有吸引力的方法。特别是邻苯甲酰羟胺作为一种亲电胺化剂,在学术和工业研究中都被证明是最好和最广泛的。在这篇综述中,我们重点介绍了最近使用邻苯甲酰羟胺作为胺化剂的过渡金属催化的C-N键形成反应及其相关的机制见解。图形抽象
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O-Benzoylhydroxylamines: A Versatile Electrophilic Aminating Reagent for Transition Metal-Catalyzed C–N Bond-Forming Reactions

Owing to the prevalence of nitrogen-containing compounds in natural products and important pharmaceutical agents, chemists, have actively searched for the development of efficient and selective methodologies allowing for the facile construction of carbon–nitrogen bonds. Over the last decade, transition metal-catalyzed C–N bond construction via electrophilic amination reaction has emerged as an attractive approach for the synthesis of various organic molecules and pharmaceuticals. Particularly, O-benzoylhydroxylamines as an electrophilic aminating agent have proven to be the best and most widely used in both academic and industrial research. In this review, we highlight the key contributions to the recent transition metal-catalyzed C–N bond formation reactions using O-benzoylhydroxylamines as an aminating agent and their relevant mechanistic insights.

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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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