异奎宁环类化合物的意外异构化

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC Journal of Physical Organic Chemistry Pub Date : 2023-05-10 DOI:10.1002/poc.4518
Rebeca G. Moura, Patrick R. Batista, Lucas C. Ducati, Lydia F. Yamaguchi, Liliana Marzorati
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引用次数: 0

摘要

三种手性二氢-2H-[2,3-a]恶唑并吡啶与N-甲基马来酰亚胺的Diels–Alder反应得到了相应的手性环加合物作为非对映体混合物。在溶剂存在下,一些最初形成的加合物发生异构化,生成新的异奎宁环。
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An unexpected isomerisation of Isoquinuclidines

The Diels–Alder reaction of three chiral dihydro-2H-[2,3-a]oxazolopyridines with N-methylmaleimide afforded the corresponding chiral cycloadducts as diastereomeric mixtures. In the presence of a solvent, some of the originally formed adducts underwent isomerisation to new isoquinuclidines.

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来源期刊
CiteScore
3.60
自引率
11.10%
发文量
161
审稿时长
2.3 months
期刊介绍: The Journal of Physical Organic Chemistry is the foremost international journal devoted to the relationship between molecular structure and chemical reactivity in organic systems. It publishes Research Articles, Reviews and Mini Reviews based on research striving to understand the principles governing chemical structures in relation to activity and transformation with physical and mathematical rigor, using results derived from experimental and computational methods. Physical Organic Chemistry is a central and fundamental field with multiple applications in fields such as molecular recognition, supramolecular chemistry, catalysis, photochemistry, biological and material sciences, nanotechnology and surface science.
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