微流反应器中高活性有机锂化合物对三氯硅烷的选择性单取代

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Flow Chemistry Pub Date : 2022-12-27 DOI:10.1007/s41981-022-00254-w
Moritz Achternbosch, Lukas Zibula, Annika Schmidt, Waldemar Krieger, Norbert Kockmann, Carsten Strohmann
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引用次数: 0

摘要

近年来,有机锂化合物已成功地应用于流动化学。大多数研究涉及卤素-锂交换的应用。然而,到目前为止,在取代反应中还缺乏使用。流动微反应器的使用使高活性有机锂化合物更加可控,从而创造了新的合成可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Selective monosubstitution on a trichlorosilane with highly reactive organolithium compounds in a microflow reactor

Organolithium compounds have been used successfully in flow chemistry since the recent past. Most of the studies dealt with the use in halogen-lithium exchanges. So far, however, there has been a lack of use in substitution reactions. The use of flow microreactors makes the highly reactive organolithium compounds more controllable and thus creates new synthetic possibilities.

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来源期刊
Journal of Flow Chemistry
Journal of Flow Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
6.40
自引率
3.70%
发文量
29
审稿时长
>12 weeks
期刊介绍: The main focus of the journal is flow chemistry in inorganic, organic, analytical and process chemistry in the academic research as well as in applied research and development in the pharmaceutical, agrochemical, fine-chemical, petro- chemical, fragrance industry.
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