手性磷酸催化金属配合物的不对称催化研究进展

IF 7.1 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Topics in Current Chemistry Pub Date : 2019-12-27 DOI:10.1007/s41061-019-0263-2
Pu-Sheng Wang, Dian-Feng Chen, Liu-Zhu Gong
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引用次数: 31

摘要

不对称金属/有机接力催化,利用金属配合物和手性有机催化剂在一锅级联反应中,旨在通过不同的催化剂在多个步骤上依次激活。这种催化结合了金属催化和有机催化的优点,提供了阶梯经济,更重要的是,有可能通过单一催化剂实现难以达到的反应性。手性磷酸是最强大的有机催化剂之一,呈现广泛的对映选择性成键反应。金属配合物和手性磷酸在单一容器中的结合已被充分记录。特别是自2008年以来,金属配合物与手性磷酸的不对称接力催化得到了迅速发展。从2008年到2014年初,已经发表了几篇优秀的综述,几乎涵盖了该领域的所有例子;因此,在本章中,我们将重点介绍2014年至2019年中期的进展情况。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent Progress in Asymmetric Relay Catalysis of Metal Complex with Chiral Phosphoric Acid

Asymmetric metal/organo relay catalysis, utilizing a metal complex and a chiral organocatalyst in a one-pot cascade reaction, is aimed to sequentially impart activation on multiple steps by distinct catalysts. Such a catalysis merges the advantages of both metal catalysis and organocatalysis, providing step-economy, and, more importantly, the potential to achieve inaccessible reactivity by a single catalyst. Chiral phosphoric acids are among the most robust organocatalysts, rendering a broad range of enantioselective bond-forming reactions. The combination of metal complexes and chiral phosphoric acids in a single vessel has been well documented. In particular, the asymmetric relay catalysis of metal complex with chiral phosphoric acid has grown rapidly since 2008. Several excellent reviews have been published to cover almost all examples in this area from 2008 to early 2014; therefore, in this chapter, we will mainly highlight progress from 2014 to mid-2019.

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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry Chemistry-General Chemistry
CiteScore
13.70
自引率
1.20%
发文量
48
期刊介绍: Topics in Current Chemistry is a journal that presents critical reviews of present and future trends in modern chemical research. It covers all areas of chemical science, including interactions with related disciplines like biology, medicine, physics, and materials science. The articles in this journal are organized into thematic collections, offering a comprehensive perspective on emerging research to non-specialist readers in academia or industry. Each review article focuses on one aspect of the topic and provides a critical survey, placing it in the context of the collection. Selected examples highlight significant developments from the past 5 to 10 years. Instead of providing an exhaustive summary or extensive data, the articles concentrate on methodological thinking. This approach allows non-specialist readers to understand the information fully and presents the potential prospects for future developments.
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