氯盐腐蚀机理及其在航天器结构中的应用

Long-kui Zhu
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引用次数: 0

摘要

如今,许多全球航天器都是在海洋环境中发射、运输或服役的,但腐蚀性的氯化物盐会侵蚀它们的结构。本文认为,低载荷下的氯盐腐蚀失效包括点蚀、点蚀向SCC转变、SCC和脆韧性断裂。在凹坑到SCC的转变过程中,基于晶体学特征定量地表达了解理面上的法向应力、施加的应力和晶体取向之间的关系。典型的脆性-韧性断裂模式是解理和剪切的连续或同时发生。采用应力强度因子和裂纹长度来评估结构实体内部的无预兆SCC和HE失效。腐蚀面积和深度、重量变化和电流密度通常用于表征多尺度航天器结构的一般腐蚀损伤。此外,应从防腐材料、使用环境和集中应力三个方面系统地保护氯盐腐蚀。同时,在航天器的整个寿命期内,必须禁止使用酸性清洗工艺。
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Chloride Salt Corrosion Mechanisms and Their Application in Spacecraft Structures

Nowadays, numerous global spacecrafts are launched, transported, or served in marine environment, but corrosive chloride salts can attack their structures. It is considered in this paper that the chloride salt corrosion failure under low loads consists of pitting, pit-to-SCC transformation, SCC, and brittle–ductile fracture. During the pit-to-SCC transformation processes, the relationships among the normal stress on cleavage planes, the applied stress and the crystal orientations are expressed quantitatively on the basis of the crystallographic features. A typical brittle–ductile fracture mode is sequential or simultaneous occurrence of cleavage and shear. The stress intensity factor and the crack length are employed to evaluate the no-omen SCC and HE failure inside the structural solids. The corrosion area and depth, the weight change and the current density are often applied to characterization of general corrosion damage in multi-scale spacecraft structures. Further, the chloride salt corrosion should be protected systematically from three aspects of anti-corrosion materials, service environment, and concentrated stress. Meanwhile, the acidic cleaning processing must be forbidden to be used in the whole spacecraft life.

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