卫星用聚酰亚胺泡沫塑料的实验研究

Li Ma, Kai Wang, Xin Zhang, Zhenlu Zhao
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引用次数: 2

摘要

BSPIF-S-7.5A是为中国卫星研制的一种开孔低密度聚酰亚胺泡沫塑料。聚酰亚胺泡沫是具有低导热性和高玻璃化转变温度的隔热材料。对其基本物理性能、热物理性能、力学性能进行了研究。为了验证聚酰亚胺泡沫的空间环境耐受性,进行了真空脱气、热循环、总剂量辐射、热真空和原子氧测试。这种泡沫的表观芯密度低至7.5 ± 0.5 kg m−3。其开放细胞的体积百分比超过98%,有利于在轨排气。热膨胀系数小于40 × 10–6 K−1,温度范围为−170至135℃。随着温度从-130℃上升到135℃,真空中的热导率从2.7 mW(m K)−1增加到42.3 mW。经过严格的空间环境试验,导热系数降低,抗压强度略有提高,但剪切性能明显下降。聚酰亚胺泡沫覆盖聚酰亚胺薄膜,可有效抵抗原子氧侵蚀。因此,聚酰亚胺泡沫是一种优越的航天隔热材料,是卫星结构的理想材料。
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Experimental Study on Polyimide Foam for Satellite

BSPIF-S-7.5A, a kind of open cell and low-density polyimide foam was developed for Chinese satellite. The polyimide foam is thermal isolation material with low thermal conductivity and high glass transition temperature. Basic physical properties, thermal physical properties, mechanical properties have been studied. For validating space environment resistance of polyimide foam, outgassing in vacuum, thermal cycle, total dose radiation, thermal vacuum and atomic oxygen tests have been performed. The apparent core density of this foam is as low as 7.5 ± 0.5 kg m−3. Its volume percentage of open cells is over 98%, which is beneficial to outgas in orbit. Coefficient of thermal expansion is less than 40 × 10–6 K−1 in the temperature range from − 170 to 135 ℃. Thermal conductivity in vacuum increases from 2.7 to 42.3 mW (m K)−1 with temperature rising from – 130 to 135 ℃. After severe space environment tests, thermal conductivity becomes even lower, compressive strength raises slightly, but shear property declines apparently. Covered with polyimide film, polyimide foam can resist atomic oxygen erosion effectively. Therefore, the polyimide foam is superior thermal insulation material for space application, which is ideal for satellite structure.

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