A. I. Nechaev, N. S. Voronina, V. N. Strel’nikov, V. A. Val’tsifer
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Investigation of Inverse Emulsion Copolymerization Kinetics of Acrylamide and Sodium 2-Acrylamido-2-methylpropanesulfonate
The influence of the reaction conditions on the kinetics of radical inverse emulsion polymerization of acrylamide and sodium 2-acrylamido-2-methylpropanesulfonate has been investigated. The copolymerization has been performed in isooctane, dissolving the monomers in water, with sorbitan monooleate and polyoxyethylene sorbitan monooleate as surfactants and AIBN as initiator. It has been found that the regularities of the inverse emulsion copolymerization are close to these of the solution polymerization. The effect of hydrothermal treatment up to 180°С on the stability of the synthesized copolymers has been addressed. The degree of hydrolysis of the copolymer has been decreased with the increase in the content of sodium 2‑acrylamido-2-methylpropanesulfonate.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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