Ilknur Babahan-Bircan, Jomin Thomas, Mark D. Soucek
{"title":"环保型紫外光固化醇酸基非异氰酸酯聚氨酯","authors":"Ilknur Babahan-Bircan, Jomin Thomas, Mark D. Soucek","doi":"10.1007/s11998-022-00623-z","DOIUrl":null,"url":null,"abstract":"<div><p>Two non-isocyanate polyurethanes (NIPUs) were used as reactive diluents for an alkyd to obtain eco-friendly new UV-curable alkyd-polyurethane coatings. A linseed-based alkyd resin was prepared and formulated with the reactive diluents (NIPUs) and free radical photoinitiator, and then UV-cured. NMRs were used to characterize the alkyd and NIPUs and glass transition temperature (<i>T</i><sub>g</sub>) of cured alkyd-polyurethanes were evaluated by using DSC. Further, spectroscopy and thermal stability of the coatings were evaluated by using ATR-IR spectroscopy and thermogravimetric analysis (TGA), respectively. Moreover, coating properties such as pencil hardness, cross-cut adhesion, pull-off adhesion, impact resistance, and reverse impact resistance were also evaluated. It was found that crosslink density, pencil hardness, adhesion, and <i>T</i><sub>g</sub> were dependent and proportional to the amount of the NIPUs (reactive diluents) showing significant improvement in mechanical and thermal properties compared to the linseed-based alkyd resin.</p></div>","PeriodicalId":48804,"journal":{"name":"Journal of Coatings Technology and Research","volume":"19 5","pages":"1507 - 1522"},"PeriodicalIF":2.3000,"publicationDate":"2022-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Environment-friendly UV-curable alkyd-based non-isocyanate urethanes\",\"authors\":\"Ilknur Babahan-Bircan, Jomin Thomas, Mark D. Soucek\",\"doi\":\"10.1007/s11998-022-00623-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Two non-isocyanate polyurethanes (NIPUs) were used as reactive diluents for an alkyd to obtain eco-friendly new UV-curable alkyd-polyurethane coatings. A linseed-based alkyd resin was prepared and formulated with the reactive diluents (NIPUs) and free radical photoinitiator, and then UV-cured. NMRs were used to characterize the alkyd and NIPUs and glass transition temperature (<i>T</i><sub>g</sub>) of cured alkyd-polyurethanes were evaluated by using DSC. Further, spectroscopy and thermal stability of the coatings were evaluated by using ATR-IR spectroscopy and thermogravimetric analysis (TGA), respectively. Moreover, coating properties such as pencil hardness, cross-cut adhesion, pull-off adhesion, impact resistance, and reverse impact resistance were also evaluated. It was found that crosslink density, pencil hardness, adhesion, and <i>T</i><sub>g</sub> were dependent and proportional to the amount of the NIPUs (reactive diluents) showing significant improvement in mechanical and thermal properties compared to the linseed-based alkyd resin.</p></div>\",\"PeriodicalId\":48804,\"journal\":{\"name\":\"Journal of Coatings Technology and Research\",\"volume\":\"19 5\",\"pages\":\"1507 - 1522\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2022-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Coatings Technology and Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11998-022-00623-z\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Coatings Technology and Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11998-022-00623-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
Two non-isocyanate polyurethanes (NIPUs) were used as reactive diluents for an alkyd to obtain eco-friendly new UV-curable alkyd-polyurethane coatings. A linseed-based alkyd resin was prepared and formulated with the reactive diluents (NIPUs) and free radical photoinitiator, and then UV-cured. NMRs were used to characterize the alkyd and NIPUs and glass transition temperature (Tg) of cured alkyd-polyurethanes were evaluated by using DSC. Further, spectroscopy and thermal stability of the coatings were evaluated by using ATR-IR spectroscopy and thermogravimetric analysis (TGA), respectively. Moreover, coating properties such as pencil hardness, cross-cut adhesion, pull-off adhesion, impact resistance, and reverse impact resistance were also evaluated. It was found that crosslink density, pencil hardness, adhesion, and Tg were dependent and proportional to the amount of the NIPUs (reactive diluents) showing significant improvement in mechanical and thermal properties compared to the linseed-based alkyd resin.
期刊介绍：
Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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