{"title":"钨酸铋基催化剂在各种有机转化中的应用综述","authors":"Murugesan Shobika, Selvaraj Mohana Roopan","doi":"10.1007/s11243-023-00535-w","DOIUrl":null,"url":null,"abstract":"<div><p>Bismuth tungstate (Bi<sub>2</sub>WO<sub>6</sub>) has received extensive research in a numerous area, including degradation, CO<sub>2</sub> reduction, organic transformations, etc. Due to their wide range of applications, the discovery and development of effective, environmentally safe, gentle, and affordable techniques for the synthesis of bismuth tungstate are critical in organic transformations. There have been reports on variety of multicomponent reactions employing the heterogeneous catalysts Bi<sub>2</sub>O<sub>3</sub>, BiVO<sub>4</sub>, and as well Bi<sub>2</sub>WO<sub>6</sub> nanoparticle. Among other materials, Bi<sub>2</sub>WO<sub>6</sub> nanoparticles are perceived for their high reactivity at ambient temperature in an aquatic medium. The main objective of this study is to emphasize the mechanistic considerations, scope, benefits, and limits of recent catalytic improvements in the process of oxidation and other reactions. Consequently, the use of Bi<sub>2</sub>WO<sub>6</sub> catalyst offers many advantages, including high yields, an ecologically friendly process, quick reaction times, and a straightforward work-up technique. It has been created to use a Bi<sub>2</sub>WO<sub>6</sub> catalyst in an aqueous medium in a versatile, simple, one-pot, multi-component technique. This process offers easy-to-find, inexpensive reagents, quick reaction times, great yields, and high atom economy. In this review, we have elaborated how Bi<sub>2</sub>WO<sub>6</sub> nanomaterials can be employed as effective and reusable catalysts for organic transformation.\n</p><h3>Graphical abstract</h3>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":803,"journal":{"name":"Transition Metal Chemistry","volume":"48 4","pages":"195 - 213"},"PeriodicalIF":1.6000,"publicationDate":"2023-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"An overview of bismuth tungstate-based catalysts in various organic transformations\",\"authors\":\"Murugesan Shobika, Selvaraj Mohana Roopan\",\"doi\":\"10.1007/s11243-023-00535-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Bismuth tungstate (Bi<sub>2</sub>WO<sub>6</sub>) has received extensive research in a numerous area, including degradation, CO<sub>2</sub> reduction, organic transformations, etc. Due to their wide range of applications, the discovery and development of effective, environmentally safe, gentle, and affordable techniques for the synthesis of bismuth tungstate are critical in organic transformations. There have been reports on variety of multicomponent reactions employing the heterogeneous catalysts Bi<sub>2</sub>O<sub>3</sub>, BiVO<sub>4</sub>, and as well Bi<sub>2</sub>WO<sub>6</sub> nanoparticle. Among other materials, Bi<sub>2</sub>WO<sub>6</sub> nanoparticles are perceived for their high reactivity at ambient temperature in an aquatic medium. The main objective of this study is to emphasize the mechanistic considerations, scope, benefits, and limits of recent catalytic improvements in the process of oxidation and other reactions. Consequently, the use of Bi<sub>2</sub>WO<sub>6</sub> catalyst offers many advantages, including high yields, an ecologically friendly process, quick reaction times, and a straightforward work-up technique. It has been created to use a Bi<sub>2</sub>WO<sub>6</sub> catalyst in an aqueous medium in a versatile, simple, one-pot, multi-component technique. This process offers easy-to-find, inexpensive reagents, quick reaction times, great yields, and high atom economy. In this review, we have elaborated how Bi<sub>2</sub>WO<sub>6</sub> nanomaterials can be employed as effective and reusable catalysts for organic transformation.\\n</p><h3>Graphical abstract</h3>\\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\\n </div>\",\"PeriodicalId\":803,\"journal\":{\"name\":\"Transition Metal Chemistry\",\"volume\":\"48 4\",\"pages\":\"195 - 213\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2023-06-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transition Metal Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11243-023-00535-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transition Metal Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11243-023-00535-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
An overview of bismuth tungstate-based catalysts in various organic transformations
Bismuth tungstate (Bi2WO6) has received extensive research in a numerous area, including degradation, CO2 reduction, organic transformations, etc. Due to their wide range of applications, the discovery and development of effective, environmentally safe, gentle, and affordable techniques for the synthesis of bismuth tungstate are critical in organic transformations. There have been reports on variety of multicomponent reactions employing the heterogeneous catalysts Bi2O3, BiVO4, and as well Bi2WO6 nanoparticle. Among other materials, Bi2WO6 nanoparticles are perceived for their high reactivity at ambient temperature in an aquatic medium. The main objective of this study is to emphasize the mechanistic considerations, scope, benefits, and limits of recent catalytic improvements in the process of oxidation and other reactions. Consequently, the use of Bi2WO6 catalyst offers many advantages, including high yields, an ecologically friendly process, quick reaction times, and a straightforward work-up technique. It has been created to use a Bi2WO6 catalyst in an aqueous medium in a versatile, simple, one-pot, multi-component technique. This process offers easy-to-find, inexpensive reagents, quick reaction times, great yields, and high atom economy. In this review, we have elaborated how Bi2WO6 nanomaterials can be employed as effective and reusable catalysts for organic transformation.
期刊介绍:
Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc.
Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.