Diptiranjan Paital, Tapasi Sen, Amitava Patra, Krishna Kanta Haldar
{"title":"核心尺寸很重要!高拉曼增强核可调金/银双金属核壳纳米粒子","authors":"Diptiranjan Paital, Tapasi Sen, Amitava Patra, Krishna Kanta Haldar","doi":"10.1007/s13404-017-0220-1","DOIUrl":null,"url":null,"abstract":"<p>Bimetallic core-shell nanostructures have been attracted tremendous attention due to their ability to form novel materials with unique chemical, optical, and physical properties. Here, we have studied the influence of core size of Au/Ag bimetallic core-shell nanostructures on the Raman enhancement efficiency with the Raman-active probe methylene blue. The surface-enhanced Raman scattering intensity is increased with increase in the core size of Au/Ag bimetallic core-shell nanoparticles. Interestingly, the enhancement factor is found to be 6.58?×?10<sup>7</sup> for the Au<sub>100</sub>/Ag core-shell nanoparticles and allows easy detection of analyte methylene blue. Thus, surface-enhanced Raman scattering properties of the metal nanoparticles are significantly enhanced due to the Au/Ag core-shell structures and the enhancement factor is dependent on the size of the core of the bimetallic nanoparticles.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"50 4","pages":"313 - 317"},"PeriodicalIF":2.2000,"publicationDate":"2017-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-017-0220-1","citationCount":"9","resultStr":"{\"title\":\"Core size matters! High Raman enhancing core tunable Au/Ag bimetallic core-shell nanoparticles\",\"authors\":\"Diptiranjan Paital, Tapasi Sen, Amitava Patra, Krishna Kanta Haldar\",\"doi\":\"10.1007/s13404-017-0220-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Bimetallic core-shell nanostructures have been attracted tremendous attention due to their ability to form novel materials with unique chemical, optical, and physical properties. Here, we have studied the influence of core size of Au/Ag bimetallic core-shell nanostructures on the Raman enhancement efficiency with the Raman-active probe methylene blue. The surface-enhanced Raman scattering intensity is increased with increase in the core size of Au/Ag bimetallic core-shell nanoparticles. Interestingly, the enhancement factor is found to be 6.58?×?10<sup>7</sup> for the Au<sub>100</sub>/Ag core-shell nanoparticles and allows easy detection of analyte methylene blue. Thus, surface-enhanced Raman scattering properties of the metal nanoparticles are significantly enhanced due to the Au/Ag core-shell structures and the enhancement factor is dependent on the size of the core of the bimetallic nanoparticles.</p>\",\"PeriodicalId\":55086,\"journal\":{\"name\":\"Gold Bulletin\",\"volume\":\"50 4\",\"pages\":\"313 - 317\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2017-10-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s13404-017-0220-1\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Gold Bulletin\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13404-017-0220-1\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Gold Bulletin","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13404-017-0220-1","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
Bimetallic core-shell nanostructures have been attracted tremendous attention due to their ability to form novel materials with unique chemical, optical, and physical properties. Here, we have studied the influence of core size of Au/Ag bimetallic core-shell nanostructures on the Raman enhancement efficiency with the Raman-active probe methylene blue. The surface-enhanced Raman scattering intensity is increased with increase in the core size of Au/Ag bimetallic core-shell nanoparticles. Interestingly, the enhancement factor is found to be 6.58?×?107 for the Au100/Ag core-shell nanoparticles and allows easy detection of analyte methylene blue. Thus, surface-enhanced Raman scattering properties of the metal nanoparticles are significantly enhanced due to the Au/Ag core-shell structures and the enhancement factor is dependent on the size of the core of the bimetallic nanoparticles.
期刊介绍:
Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.