{"title":"汽车三路反应用串联贱金属氧化物催化剂:优先氧化烃类的MnFe2O4","authors":"Keisuke Maruichi, Ryosuke Sakai, Kakuya Ueda, Akira Oda, Atsushi Satsuma","doi":"10.1007/s10563-022-09373-9","DOIUrl":null,"url":null,"abstract":"<div><p>A combination of two base-metal oxides in tandem configuration can realize three-way reaction without platinum group metals. For this purpose, catalysts for hydrocarbon preferential oxidation (HC-PROX) and for NO reduction by CO are required. For the design of HC-PROX catalysts, competitive oxidation of propene and CO on spinel-type MFe<sub>2</sub>O<sub>4</sub> (M = Co, Cu, Mg, Mn, Ni, Zn) was investigated. MnFe<sub>2</sub>O<sub>4</sub> preferentially oxidized propene in the co-presence of CO showing the best propene oxidation activity. Among the series of MFe<sub>2</sub>O<sub>4</sub>, the activity controlling factor was correlated to the M-O bond energy of the second metal oxides, and the preference for HC oxidation was dependent on the electronegativity of the second ion. A tandem catalyst using MnFe<sub>2</sub>O<sub>4</sub> for HC-PROX and CuCo<sub>2</sub>O<sub>4</sub> for NO-CO reaction showed TWC activity comparable to a Rh/CeO<sub>2</sub>.</p></div>","PeriodicalId":509,"journal":{"name":"Catalysis Surveys from Asia","volume":"27 1","pages":"48 - 55"},"PeriodicalIF":2.1000,"publicationDate":"2022-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Tandem Base-Metal Oxide Catalyst for Automotive Three-way Reaction: MnFe2O4 for Preferential Oxidation of Hydrocarbon\",\"authors\":\"Keisuke Maruichi, Ryosuke Sakai, Kakuya Ueda, Akira Oda, Atsushi Satsuma\",\"doi\":\"10.1007/s10563-022-09373-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A combination of two base-metal oxides in tandem configuration can realize three-way reaction without platinum group metals. For this purpose, catalysts for hydrocarbon preferential oxidation (HC-PROX) and for NO reduction by CO are required. For the design of HC-PROX catalysts, competitive oxidation of propene and CO on spinel-type MFe<sub>2</sub>O<sub>4</sub> (M = Co, Cu, Mg, Mn, Ni, Zn) was investigated. MnFe<sub>2</sub>O<sub>4</sub> preferentially oxidized propene in the co-presence of CO showing the best propene oxidation activity. Among the series of MFe<sub>2</sub>O<sub>4</sub>, the activity controlling factor was correlated to the M-O bond energy of the second metal oxides, and the preference for HC oxidation was dependent on the electronegativity of the second ion. A tandem catalyst using MnFe<sub>2</sub>O<sub>4</sub> for HC-PROX and CuCo<sub>2</sub>O<sub>4</sub> for NO-CO reaction showed TWC activity comparable to a Rh/CeO<sub>2</sub>.</p></div>\",\"PeriodicalId\":509,\"journal\":{\"name\":\"Catalysis Surveys from Asia\",\"volume\":\"27 1\",\"pages\":\"48 - 55\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2022-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Surveys from Asia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10563-022-09373-9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Surveys from Asia","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10563-022-09373-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Tandem Base-Metal Oxide Catalyst for Automotive Three-way Reaction: MnFe2O4 for Preferential Oxidation of Hydrocarbon
A combination of two base-metal oxides in tandem configuration can realize three-way reaction without platinum group metals. For this purpose, catalysts for hydrocarbon preferential oxidation (HC-PROX) and for NO reduction by CO are required. For the design of HC-PROX catalysts, competitive oxidation of propene and CO on spinel-type MFe2O4 (M = Co, Cu, Mg, Mn, Ni, Zn) was investigated. MnFe2O4 preferentially oxidized propene in the co-presence of CO showing the best propene oxidation activity. Among the series of MFe2O4, the activity controlling factor was correlated to the M-O bond energy of the second metal oxides, and the preference for HC oxidation was dependent on the electronegativity of the second ion. A tandem catalyst using MnFe2O4 for HC-PROX and CuCo2O4 for NO-CO reaction showed TWC activity comparable to a Rh/CeO2.
期刊介绍：
Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.
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