{"title":"[W(η - 2- phc2ph)3(NCMe)]与邻二苯基膦-苯乙烯和-烯丙苯的反应新的碳-碳双键和三键裂解和炔插入反应的证据","authors":"G. Cairns, N. Carr, Michael J. Green, M. Mahon","doi":"10.1039/CC9960002431","DOIUrl":null,"url":null,"abstract":"Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"1 1","pages":"2431-2432"},"PeriodicalIF":4.3000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/CC9960002431","citationCount":"15","resultStr":"{\"title\":\"Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions\",\"authors\":\"G. Cairns, N. Carr, Michael J. Green, M. Mahon\",\"doi\":\"10.1039/CC9960002431\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"1 1\",\"pages\":\"2431-2432\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"1996-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/CC9960002431\",\"citationCount\":\"15\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/CC9960002431\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/CC9960002431","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions
Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.
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