共轭硝基氧

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Reviews Pub Date : 2021-01-01 DOI:10.1070/rcr5025

E. Tretyakov, V. Ovcharenko, A. Terent’ev, I. Krylov, T. Magdesieva, D. Mazhukin, N. Gritsan

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引用次数: 21

摘要

近年来，对稳定自由基和高自旋体系等有机顺磁性化合物的研究主要集中在应用方面。在有机自由基和多自由基的应用和定向合成中形成了几个关键的趋势。这篇综述解决了这样的趋势之一，其中主导作用是发挥所谓的共轭氮氧化物。它们的具体特征是存在任何不饱和基团(C=C, C=N或C=O多键;芳香或杂芳香环;熔融多芳系)与氮氧化物基团相邻。介绍了共轭氮氧化物的化学研究进展，讨论了共轭氮氧化物的物理化学性质、磁结构关系和实际应用。参考书目包括641篇参考文献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Conjugated nitroxides

In recent years, research dealing with organic paramagnetic compounds such as stable radicals and high-spin systems has been focused on applied aspects. Several key trends have formed in the application and, hence, in the function-oriented synthesis of organic radicals and polyradicals. This review addresses one of such trends in which the dominant role is played by so-called conjugated nitroxides. Their specific feature is the presence of any unsaturated moiety (C=C, C=N or C=O multiple bond; aromatic or heteroaromatic ring; fused polyaromatic system) adjacent to the nitroxide group. The achievements of the chemistry of conjugated nitroxides are presented, and their physicochemical properties, magneto-structural correlations and practical applications are discussed. The bibliography includes 641 references.

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来源期刊

Russian Chemical Reviews 化学-化学综合

CiteScore

13.00

自引率

5.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Russian Chemical Reviews serves as a complete translation of the esteemed monthly review journal Uspekhi Khimii, which has been a prominent figure in Russian scientific journals since its establishment in 1932. It offers comprehensive access to the advancements made by chemists from Russia and other former Soviet Union countries. Established in 1932, Russian Chemical Reviews is committed to publishing timely and significant review articles encompassing various facets of modern chemistry, including chemical physics, physical chemistry, computational and theoretical chemistry, catalysis, coordination chemistry, analytical chemistry, organic, organometallic, and organoelement chemistry, chemistry of macromolecules, applied chemistry, biochemistry, bio-organic chemistry, biomolecular chemistry, medicinal chemistry, materials chemistry, nanochemistry, nanostructures, and environmental chemistry.