Fan Yang, Jihui Wang, Changzeng Wang, Junlei Chen, A. Ding
{"title":"高效含磷三嗪环环氧树脂反应性阻燃剂的合成","authors":"Fan Yang, Jihui Wang, Changzeng Wang, Junlei Chen, A. Ding","doi":"10.1108/mmms-11-2022-0259","DOIUrl":null,"url":null,"abstract":"PurposeIn order to find an appropriate method to synthesize a new high-efficiency flame retardant for epoxy resin.Design/methodology/approachIn this work, a flame retardant with heterocyclic groups, HOMP, was acquired after removing the obstacle from triazines which was not readily soluble. The molecular structure, thermal and flame retardant properties were fully characterized and analyzed. Also, the mechanism was researched through multi-methodologies. As well, the authors evaluated the effects of HOMP on mechanical properties.FindingsThe results suggested that HOMP helped extinguish the combustion of specimens and could reach an LOI value of 29.2% and the V0 level in the UL-94 test with a phosphorus content of only 0.6wt%. With respect to the mechanism, HOMP was a gas-phase flame retardant and helped generate a thicker carbon protective coating. However, for the mechanical properties, the addition of HOMP enhanced the compressibility, while the tensile strength decreased significantly.Originality/valueThe approach not only simplified the operations but also obtained HOMP with excellent flame retardant properties.","PeriodicalId":46760,"journal":{"name":"Multidiscipline Modeling in Materials and Structures","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis of an efficient phosphorus and triazine ring-containing reactive flame retardant for epoxy resin\",\"authors\":\"Fan Yang, Jihui Wang, Changzeng Wang, Junlei Chen, A. Ding\",\"doi\":\"10.1108/mmms-11-2022-0259\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"PurposeIn order to find an appropriate method to synthesize a new high-efficiency flame retardant for epoxy resin.Design/methodology/approachIn this work, a flame retardant with heterocyclic groups, HOMP, was acquired after removing the obstacle from triazines which was not readily soluble. The molecular structure, thermal and flame retardant properties were fully characterized and analyzed. Also, the mechanism was researched through multi-methodologies. As well, the authors evaluated the effects of HOMP on mechanical properties.FindingsThe results suggested that HOMP helped extinguish the combustion of specimens and could reach an LOI value of 29.2% and the V0 level in the UL-94 test with a phosphorus content of only 0.6wt%. With respect to the mechanism, HOMP was a gas-phase flame retardant and helped generate a thicker carbon protective coating. However, for the mechanical properties, the addition of HOMP enhanced the compressibility, while the tensile strength decreased significantly.Originality/valueThe approach not only simplified the operations but also obtained HOMP with excellent flame retardant properties.\",\"PeriodicalId\":46760,\"journal\":{\"name\":\"Multidiscipline Modeling in Materials and Structures\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Multidiscipline Modeling in Materials and Structures\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1108/mmms-11-2022-0259\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Multidiscipline Modeling in Materials and Structures","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1108/mmms-11-2022-0259","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of an efficient phosphorus and triazine ring-containing reactive flame retardant for epoxy resin
PurposeIn order to find an appropriate method to synthesize a new high-efficiency flame retardant for epoxy resin.Design/methodology/approachIn this work, a flame retardant with heterocyclic groups, HOMP, was acquired after removing the obstacle from triazines which was not readily soluble. The molecular structure, thermal and flame retardant properties were fully characterized and analyzed. Also, the mechanism was researched through multi-methodologies. As well, the authors evaluated the effects of HOMP on mechanical properties.FindingsThe results suggested that HOMP helped extinguish the combustion of specimens and could reach an LOI value of 29.2% and the V0 level in the UL-94 test with a phosphorus content of only 0.6wt%. With respect to the mechanism, HOMP was a gas-phase flame retardant and helped generate a thicker carbon protective coating. However, for the mechanical properties, the addition of HOMP enhanced the compressibility, while the tensile strength decreased significantly.Originality/valueThe approach not only simplified the operations but also obtained HOMP with excellent flame retardant properties.