镁电池用双酰胺基电解液集流材料的耐腐蚀性能

Clemens Wall, Z. Zhao‐Karger, M. Fichtner
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引用次数: 55

摘要

研究了Ti、Cr、Ni、Fe、Al、304钢、Inconel 625、哈氏合金B和碳包覆集流器与铋酰胺基电解质的相容性。由3d过渡金属和304钢制成的集流器在2.2 ~ 3.1 V vs. Mg/Mg2+电位范围内观察到点蚀现象。Inconel 625、Hastelloy B、石墨和碳涂层Al箔的阳极稳定性高达3.8 V,在2.5 V vs. Mg/Mg2+及以上电位下耐腐蚀48 h。©作者2014。由ECS出版。这是一篇在知识共享署名非商业禁止衍生品4.0许可(CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/)条款下发布的开放获取文章,该许可允许在任何媒介上进行非商业重用、分发和复制,前提是原始作品不以任何方式改变并适当引用。如需商业使用许可,请发邮件至oa@electrochem.org。[DOI: 10.1149/2.0111501]版权所有。
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Corrosion Resistance of Current Collector Materials in Bisamide Based Electrolyte for Magnesium Batteries
The compatibility of Ti, Cr, Ni, Fe, Al, steel type 304, Inconel 625, Hastelloy B and carbon coated current collectors with bisamide based electrolyte for Mg-batteries was investigated. Pitting corrosion of current collectors made from 3d-transition metals and steel type 304 was observed at potentials between 2.2–3.1 V vs. Mg/Mg2+. Anodic stability up to 3.8 V and resistance against corrosion for 48 h at a potential of 2.5 V vs. Mg/Mg2+ and above was found for Inconel 625, Hastelloy B, graphite and carbon coated Al foil. © The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0111501eel] All rights reserved.
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来源期刊
ECS Electrochemistry Letters
ECS Electrochemistry Letters ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY
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