Oscar Felipe Arbeláez Pérez, Víctor Ignacio López Ríos, Aída Luz Villa Holguín, Adriana Patricia Villegas Quiceno
{"title":"测定双金属铜镍催化剂颗粒大小对水置换反应的影响的实验设计","authors":"Oscar Felipe Arbeláez Pérez, Víctor Ignacio López Ríos, Aída Luz Villa Holguín, Adriana Patricia Villegas Quiceno","doi":"10.15446/REV.COLOMB.QUIM.V47N1.64699","DOIUrl":null,"url":null,"abstract":"Bimetallic Cu-Ni catalysts were synthesized with molar ratio 2-1 in cylindrical activated carbon pellets of different diameters (0.2 cm, 0.3 cm, and 0.4 cm) and length (0.4 cm and 0.6 cm). They were evaluated in the water gas shift reaction at 330 °C and atmospheric pressure. An experimental design was developed to evaluate the effect of variables, diameter and length of the pellets, over carbon monoxide conversion. The importance of the main factors and their interactions were examined by analysis of variance (ANOVA). The results showed that both diameter and length of the pellets had significant effect on carbon monoxide conversion. The results of the catalytic activity indicated that up to 96% CO conversion was obtained at the optimum characteristic of the pellets, diameter of 0.2 cm and length of 0.6 cm.","PeriodicalId":43662,"journal":{"name":"Revista Colombiana de Quimica","volume":null,"pages":null},"PeriodicalIF":0.2000,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.15446/REV.COLOMB.QUIM.V47N1.64699","citationCount":"3","resultStr":"{\"title\":\"Diseño experimental para determinar el efecto del tamaño del pellet de catalizadores bimetálicos Cu-Ni en la reacción de desplazamiento de agua\",\"authors\":\"Oscar Felipe Arbeláez Pérez, Víctor Ignacio López Ríos, Aída Luz Villa Holguín, Adriana Patricia Villegas Quiceno\",\"doi\":\"10.15446/REV.COLOMB.QUIM.V47N1.64699\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Bimetallic Cu-Ni catalysts were synthesized with molar ratio 2-1 in cylindrical activated carbon pellets of different diameters (0.2 cm, 0.3 cm, and 0.4 cm) and length (0.4 cm and 0.6 cm). They were evaluated in the water gas shift reaction at 330 °C and atmospheric pressure. An experimental design was developed to evaluate the effect of variables, diameter and length of the pellets, over carbon monoxide conversion. The importance of the main factors and their interactions were examined by analysis of variance (ANOVA). The results showed that both diameter and length of the pellets had significant effect on carbon monoxide conversion. The results of the catalytic activity indicated that up to 96% CO conversion was obtained at the optimum characteristic of the pellets, diameter of 0.2 cm and length of 0.6 cm.\",\"PeriodicalId\":43662,\"journal\":{\"name\":\"Revista Colombiana de Quimica\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.2000,\"publicationDate\":\"2018-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.15446/REV.COLOMB.QUIM.V47N1.64699\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Revista Colombiana de Quimica\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15446/REV.COLOMB.QUIM.V47N1.64699\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Revista Colombiana de Quimica","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15446/REV.COLOMB.QUIM.V47N1.64699","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Diseño experimental para determinar el efecto del tamaño del pellet de catalizadores bimetálicos Cu-Ni en la reacción de desplazamiento de agua
Bimetallic Cu-Ni catalysts were synthesized with molar ratio 2-1 in cylindrical activated carbon pellets of different diameters (0.2 cm, 0.3 cm, and 0.4 cm) and length (0.4 cm and 0.6 cm). They were evaluated in the water gas shift reaction at 330 °C and atmospheric pressure. An experimental design was developed to evaluate the effect of variables, diameter and length of the pellets, over carbon monoxide conversion. The importance of the main factors and their interactions were examined by analysis of variance (ANOVA). The results showed that both diameter and length of the pellets had significant effect on carbon monoxide conversion. The results of the catalytic activity indicated that up to 96% CO conversion was obtained at the optimum characteristic of the pellets, diameter of 0.2 cm and length of 0.6 cm.
期刊介绍:
The Revista Colombiana de Química - Colombian Journal of Chemistry (Rev. Colomb. Quim.) Is a peer-reviewed scientific journal of the Department of Chemistry, Faculty of Sciences of the Universidad Nacional de Colombia, Bogotá. It currently publishes three volumes per year: January-April, May-August and September-December. All the content published by the Journal (available online) is under a Creative Commons attribution license type BY 4.0, that allows any person or entity in the world to freely access the content, share it, download it, adapt it or make derivative works without any restriction, provided that it adequately indicates the credit to the authors and to the Colombian Journal of Chemistry.