水处理膜的性能改进策略:MXene和GO

IF 5.9 3区 材料科学 Q2 CHEMISTRY, PHYSICAL FlatChem Pub Date : 2023-09-09 DOI:10.1016/j.flatc.2023.100548
Ke-xin Tao , Li-yue Sun , De-hao Yu , Chen-yu Jia , Zhao-ge Juan , Yao Wang , Yan-xin Wang , Matt J. Kipper , Lin-jun Huang , Jian-guo Tang
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引用次数: 0

摘要

水资源的短缺将继续推动对水净化技术的需求。膜分离以其对环境影响小、效率高、成本低、操作方便等优点,已成为水处理中最常用的技术。该技术在海水淡化、纺织废水染料和盐的分离、油水分离、重金属离子的去除和抗菌材料等领域得到了广泛的应用。二维(2D)层状材料表面的孔隙和片层堆叠形成的纳米级层间距可以为溶液提供有效的通过路径。通过调节表面孔隙的数量、直径和层间距,使盐离子、大分子等从水溶液中分离出来,以满足工业和生活的需要。氧化石墨烯(GO)家族由于其独特的二维层状结构,在水处理领域得到了广泛的应用。MXene自2011年被发现以来,已成为继GO之后在水处理领域最有前途的新型二维材料。虽然氧化石墨烯膜和MXene膜在水处理领域占有重要地位,但仍存在水通量低、截留率低、稳定性差、制造工艺复杂等技术难题,限制了它们的广泛应用。为了系统地了解和解决上述问题,本文对两种材料的结构、制备方法、膜性能、水处理原理和优化策略以及在水处理中的应用等方面进行了比较和分析。总结了各种常用的材料制备方法,并重点介绍了解决当前水处理膜问题可实施的性能优化策略。对比分析表明,氧化石墨烯的制备方法比MXene的制备方法更为成熟。氧化石墨烯膜可能具有稍高的亲水性,但相对较低的水通量。膜的性能可以通过化学和物理改性来控制,包括化学交联、插层和表面改性,以获得膜分离性能的改善。这项工作将有助于研究人员根据具体需求选择更合适的材料和制备方法,并总结出制备应用范围更广、质量更高的GO和MXene膜的条件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Performance improvement strategy for water treatment films: MXene and GO

The shortage of water resources will continue to drive the need for technologies for water purification. Membrane separation has become the most commonly used technology for water treatment due to its low environmental impact, high efficiency, low cost and convenient operation. This technology has found widespread applications in various fields such as desalination, the separation of textile wastewater dyes and salts, oil–water separation, removal of heavy metal ions and antibacterial materials. The pores on the surface of the two-dimensional (2D)layered materials and the nano-scale interlayer spacing formed by the stacking of sheets can provide an effective path for the solution to pass through. By adjusting the number and diameter of the surface pores and the interlayer spacing that salt ions and macromolecular etc. are separated from the aqueous solution to meet the needs of industry and life. The graphene oxide (GO) family has been widely used in water treatment for decades due to it's unique layered 2D structure. Since its discovery in 2011, MXene has become the most promising new 2D material after GO in the field of water treatment. Although GO and MXene membranes have occupied important positions in the field of water treatment, some technological challenges still limit their widespread application, including low water flux, low rejection rate, low stability and complicated manufacturing processes. To systematically understand and solve the above problems, this paper compares and analyzes the similarities and differences between the two materials including their structure, preparation methods, membrane performance, water treatment principle and optimization strategies, and applications in water treatment. A variety of commonly used materials preparation methods are summarized, and the performance optimization strategies that can be implemented to solve the current water treatment membrane problems are highlighted. The comparative analysis reveals that the preparation methods for GO are more mature than those of MXene. GO membranes may achieve slightly higher hydrophilicity, but relatively lower water flux. The properties of the membranes can be controlled by chemical and physical modifications, including chemical crosslinking, intercalation, and surface modification to obtain performance improvement for membrane separation. This work will help researchers to choose more suitable materials and preparation methods tailored to specific needs, and it summarizes conditions for the preparation of GO and MXene membranes with wider application range and higher quality.

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来源期刊
FlatChem
FlatChem Multiple-
CiteScore
8.40
自引率
6.50%
发文量
104
审稿时长
26 days
期刊介绍: FlatChem - Chemistry of Flat Materials, a new voice in the community, publishes original and significant, cutting-edge research related to the chemistry of graphene and related 2D & layered materials. The overall aim of the journal is to combine the chemistry and applications of these materials, where the submission of communications, full papers, and concepts should contain chemistry in a materials context, which can be both experimental and/or theoretical. In addition to original research articles, FlatChem also offers reviews, minireviews, highlights and perspectives on the future of this research area with the scientific leaders in fields related to Flat Materials. Topics of interest include, but are not limited to, the following: -Design, synthesis, applications and investigation of graphene, graphene related materials and other 2D & layered materials (for example Silicene, Germanene, Phosphorene, MXenes, Boron nitride, Transition metal dichalcogenides) -Characterization of these materials using all forms of spectroscopy and microscopy techniques -Chemical modification or functionalization and dispersion of these materials, as well as interactions with other materials -Exploring the surface chemistry of these materials for applications in: Sensors or detectors in electrochemical/Lab on a Chip devices, Composite materials, Membranes, Environment technology, Catalysis for energy storage and conversion (for example fuel cells, supercapacitors, batteries, hydrogen storage), Biomedical technology (drug delivery, biosensing, bioimaging)
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