生物质、煤和半焦在不同加热条件下的反应性

IF 0.4 Q4 ENGINEERING, CHEMICAL Coke and Chemistry Pub Date : 2023-09-13 DOI:10.3103/S1068364X23700850
A. V. Zhuikov, S. G. Stepanov, D. A. Loginov
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引用次数: 0

摘要

研究了生物质、煤和半焦(煤在700-800℃部分气化得到)的反应性和非等温加热条件;具体地说,确定了燃料的平均反应指数。此外,还研究了它们在热空气对流加热中的反应性;确定了点火延迟时间。非等温加热伴随着同步热分析在空气通量(加热速率20°C/min)。在空气对流加热中(500 ~ 800℃,流速~ 5m /s),实验系统包括一个内置水平石英管的马弗炉;燃油点火过程由高速摄像机记录下来。在这两种加热方式中,生物质的反应性最强。在热空气对流加热中,由于颗粒的表面积更大,半焦的点火延迟比煤小。在非等温加热中,半焦的平均反应指数(1.6 min°C-1)低于生物质(7.0 min°C-1)和煤(4.1 min°C-1)。这表明在给定的加热条件下反应性较低。
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Reactivity of Biomass, Coal, and Semicoke in Different Heating Conditions

The reactivity and conditions of nonisothermal heating are investigated for biomass, coal, and semicoke (obtained by partial gasification of coal at 700–800°C) are investigated; specifically, the mean reactive index of the fuels is determined. In addition, their reactivity in convective heating by hot air is studied; the delay time in ignition is determined. Nonisothermal heating is accompanied by synchronous thermal analysis in an air flux (heating rate 20°C/min). In convective heating by an air flux (500–800°C, flow rate ~5 m/s), the experimental system includes a muffle furnace with a built in horizontal quartz tube; fuel ignition is recorded by means of a high-speed video camera. In both types of heating, biomass is the most reactive. In convective heating by hot air, the ignition delay is less for semicoke than for coal, on account of the greater surface area of the particles. In nonisothermal heating, the mean reactive index of the semicoke (1.6 min °C–1) is lower than for the biomass (7.0 min °C–1) and the coal (4.1 min °C–1). That indicates lower reactivity in the given heating conditions.

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来源期刊
Coke and Chemistry
Coke and Chemistry ENGINEERING, CHEMICAL-
CiteScore
0.70
自引率
50.00%
发文量
36
期刊介绍: The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.
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