V. Takeshita, K. F. Mendes, R. F. Pimpinato, V. L. Tornisielo
{"title":"四种农工废渣对饮用水中二脲和己嗪酮的吸附等温线","authors":"V. Takeshita, K. F. Mendes, R. F. Pimpinato, V. L. Tornisielo","doi":"10.1590/s0100-83582020380100013","DOIUrl":null,"url":null,"abstract":"ABSTRACT: Materials with high organic carbon content are studied for the removal of herbicides from water, such as activated carbon. Low cost alternatives should be investigated for the substitution of this type of material in the removal of herbicides from water. In this context, the aim of this research was to evaluate four agro-industrial residues (white grape bagasse, corn straw, peanut shell and soybean hull) as adsorbents of diuron and hexazinone in drinking water. Samples of drinking water were collected from sources used for human consumption. Five concentrations (1, 2, 3, 4 and 5 mg mL-1) of each herbicide were added to the potable water samples. Each experimental unit consisted of 10 mL of a solution of water and herbicide with 0.1 g of each agro-industrial residue. Sorption was evaluated using the batch equilibrium method. High performance liquid chromatography (HPLC) was used to determine the amount of herbicide present in the aqueous solution. The Kf (Freundlich coefficient) of diuron was higher (2.99-11.93 mmol(1-1/n) L1/n kg-1) than hexazinone (2.31-4.61 mmol(1-1/n) L1/n kg-1) for all adsorbents used. Diuron percentage sorption was higher with white grape bagasse (51.15%) and peanut husk (52.44%), and hexazinone with corn straw (22.77%) and white grape marc (21.48%), than other agro-industrial waste for both herbicides. Even though the sorption of diuron was more pronounced than that of hexazinone, the sorption values obtained in this study were less than 52.44% and considered unsatisfactory in terms of effective removal from contaminated water.","PeriodicalId":20102,"journal":{"name":"Planta Daninha","volume":"38 1","pages":""},"PeriodicalIF":0.8000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Adsorption Isotherms of Diuron and Hexazinone in Drinking Water Using Four Agro-Industrial Residues\",\"authors\":\"V. Takeshita, K. F. Mendes, R. F. Pimpinato, V. L. Tornisielo\",\"doi\":\"10.1590/s0100-83582020380100013\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT: Materials with high organic carbon content are studied for the removal of herbicides from water, such as activated carbon. Low cost alternatives should be investigated for the substitution of this type of material in the removal of herbicides from water. In this context, the aim of this research was to evaluate four agro-industrial residues (white grape bagasse, corn straw, peanut shell and soybean hull) as adsorbents of diuron and hexazinone in drinking water. Samples of drinking water were collected from sources used for human consumption. Five concentrations (1, 2, 3, 4 and 5 mg mL-1) of each herbicide were added to the potable water samples. Each experimental unit consisted of 10 mL of a solution of water and herbicide with 0.1 g of each agro-industrial residue. Sorption was evaluated using the batch equilibrium method. High performance liquid chromatography (HPLC) was used to determine the amount of herbicide present in the aqueous solution. The Kf (Freundlich coefficient) of diuron was higher (2.99-11.93 mmol(1-1/n) L1/n kg-1) than hexazinone (2.31-4.61 mmol(1-1/n) L1/n kg-1) for all adsorbents used. Diuron percentage sorption was higher with white grape bagasse (51.15%) and peanut husk (52.44%), and hexazinone with corn straw (22.77%) and white grape marc (21.48%), than other agro-industrial waste for both herbicides. Even though the sorption of diuron was more pronounced than that of hexazinone, the sorption values obtained in this study were less than 52.44% and considered unsatisfactory in terms of effective removal from contaminated water.\",\"PeriodicalId\":20102,\"journal\":{\"name\":\"Planta Daninha\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Planta Daninha\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1590/s0100-83582020380100013\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Agricultural and Biological Sciences\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Planta Daninha","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1590/s0100-83582020380100013","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
Adsorption Isotherms of Diuron and Hexazinone in Drinking Water Using Four Agro-Industrial Residues
ABSTRACT: Materials with high organic carbon content are studied for the removal of herbicides from water, such as activated carbon. Low cost alternatives should be investigated for the substitution of this type of material in the removal of herbicides from water. In this context, the aim of this research was to evaluate four agro-industrial residues (white grape bagasse, corn straw, peanut shell and soybean hull) as adsorbents of diuron and hexazinone in drinking water. Samples of drinking water were collected from sources used for human consumption. Five concentrations (1, 2, 3, 4 and 5 mg mL-1) of each herbicide were added to the potable water samples. Each experimental unit consisted of 10 mL of a solution of water and herbicide with 0.1 g of each agro-industrial residue. Sorption was evaluated using the batch equilibrium method. High performance liquid chromatography (HPLC) was used to determine the amount of herbicide present in the aqueous solution. The Kf (Freundlich coefficient) of diuron was higher (2.99-11.93 mmol(1-1/n) L1/n kg-1) than hexazinone (2.31-4.61 mmol(1-1/n) L1/n kg-1) for all adsorbents used. Diuron percentage sorption was higher with white grape bagasse (51.15%) and peanut husk (52.44%), and hexazinone with corn straw (22.77%) and white grape marc (21.48%), than other agro-industrial waste for both herbicides. Even though the sorption of diuron was more pronounced than that of hexazinone, the sorption values obtained in this study were less than 52.44% and considered unsatisfactory in terms of effective removal from contaminated water.
Planta DaninhaAgricultural and Biological Sciences-Plant Science
自引率
0.00%
发文量
0
审稿时长
16 weeks
期刊介绍:
Planta Daninha is a scientific journal published by the Brazilian Society of Weed Science (SBCPD - Sociedade Brasileira da Ciência das Plantas Daninhas). Papers submitted for publication must be sent through an electronic system, on http://www.scielo.br/pd. Works may be written in Portuguese, English, or Spanish, and will be accepted after being reviewed and approved by the Editorial Board. Only papers that have not been published or submitted for publication in other media will be accepted. Articles in Portuguese will be translated to English after being properly corrected and authorized by the authors. Planta Daninha has with goal to publish genuine technical-scientific papers and literature reviews from a critical perspective on Biology, weed management, and related topics.