纳米氧化铜作为点击反应的催化剂

Reda, Abdelhady, Mustafa, ElKhashab, Abdelaziz, Ahmed, Nayl, Elsayed, Mohamed, Badawy, TamerAbdelmoemen, Malah
{"title":"纳米氧化铜作为点击反应的催化剂","authors":"Reda, Abdelhady, Mustafa, ElKhashab, Abdelaziz, Ahmed, Nayl, Elsayed, Mohamed, Badawy, TamerAbdelmoemen, Malah","doi":"10.17265/1934-7375/2016.07.005","DOIUrl":null,"url":null,"abstract":"Click reactions are not specific reactions, but they are a way of generating products that follow examples in nature by joining small moieties, with each other producing a huge molecule in a good yield. The mind of that reaction is used in biomolecules synthesis, pharmacological and various biometric applications. The first Click reaction is the Copper compounds-catalyzed reaction of an azide with an alkyne (CuAAC), this copper-catalyzed “click” does not require legands on the metal but the metal oxides also can accelerate the reactions. For enhancement the products of Click reactions we were replacing the copper compounds in a classical reaction by the prepared nanocopper compound (NPs). And measure the consumption of starting material. Behind the evolution is the catalytic effect of nanocopper compounding (NPs) on (H2O2). Owing to the huge surface area of nanocopper compound (NPs), it was found that: the (NPs) can speed up decomposition of H2O2, also can accelerate the classical click reaction.","PeriodicalId":67212,"journal":{"name":"化学与化工:英文版","volume":"10 1","pages":"341-346"},"PeriodicalIF":0.0000,"publicationDate":"2016-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Nano-copper Oxide as Catalyst for Click Reactions\",\"authors\":\"Reda, Abdelhady, Mustafa, ElKhashab, Abdelaziz, Ahmed, Nayl, Elsayed, Mohamed, Badawy, TamerAbdelmoemen, Malah\",\"doi\":\"10.17265/1934-7375/2016.07.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Click reactions are not specific reactions, but they are a way of generating products that follow examples in nature by joining small moieties, with each other producing a huge molecule in a good yield. The mind of that reaction is used in biomolecules synthesis, pharmacological and various biometric applications. The first Click reaction is the Copper compounds-catalyzed reaction of an azide with an alkyne (CuAAC), this copper-catalyzed “click” does not require legands on the metal but the metal oxides also can accelerate the reactions. For enhancement the products of Click reactions we were replacing the copper compounds in a classical reaction by the prepared nanocopper compound (NPs). And measure the consumption of starting material. Behind the evolution is the catalytic effect of nanocopper compounding (NPs) on (H2O2). Owing to the huge surface area of nanocopper compound (NPs), it was found that: the (NPs) can speed up decomposition of H2O2, also can accelerate the classical click reaction.\",\"PeriodicalId\":67212,\"journal\":{\"name\":\"化学与化工:英文版\",\"volume\":\"10 1\",\"pages\":\"341-346\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"化学与化工:英文版\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://doi.org/10.17265/1934-7375/2016.07.005\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"化学与化工:英文版","FirstCategoryId":"1089","ListUrlMain":"https://doi.org/10.17265/1934-7375/2016.07.005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

摘要

点击反应不是特定的反应,但它们是一种生产产品的方式,遵循自然界的例子,通过将小部分连接在一起,以良好的产量产生一个大分子。该反应的思想被用于生物分子合成、药理学和各种生物计量学应用。第一个咔嗒反应是铜化合物催化叠氮化物与炔(CuAAC)的反应,这种铜催化的“咔嗒”反应不需要金属上的基团,金属氧化物也可以加速反应。为了增强Click反应的产物,我们用制备的纳米铜化合物(NPs)取代了经典反应中的铜化合物。并测量原料的消耗量。这种演变的背后是纳米铜复合物(NPs)对H2O2的催化作用。由于纳米铜化合物(NPs)的表面积大,研究发现:纳米铜化合物(NPs)可以加速H2O2的分解,也可以加速经典的咔嗒反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Nano-copper Oxide as Catalyst for Click Reactions
Click reactions are not specific reactions, but they are a way of generating products that follow examples in nature by joining small moieties, with each other producing a huge molecule in a good yield. The mind of that reaction is used in biomolecules synthesis, pharmacological and various biometric applications. The first Click reaction is the Copper compounds-catalyzed reaction of an azide with an alkyne (CuAAC), this copper-catalyzed “click” does not require legands on the metal but the metal oxides also can accelerate the reactions. For enhancement the products of Click reactions we were replacing the copper compounds in a classical reaction by the prepared nanocopper compound (NPs). And measure the consumption of starting material. Behind the evolution is the catalytic effect of nanocopper compounding (NPs) on (H2O2). Owing to the huge surface area of nanocopper compound (NPs), it was found that: the (NPs) can speed up decomposition of H2O2, also can accelerate the classical click reaction.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
934
期刊最新文献
Clinical Implications of Cross-Reactive Shellfish Allergens Relationship of Reproductive Hormones and Fertility in Patients with Beta-Thalassemia Major Multi-isotope Analysis of Tartaric Acid Derivative: Potassium Bitartrate Provenance, Guideline Values and Trace and Minor Elements in Bottom Sediments of Tebicuary River and Tapiracuai Stream from Eastern Paraguay by X-Ray Fluorescence Oligosaccharides and Glycan Separation via Capillary Electrophoresis Coupled with Mass Spectroscopy
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1