珍珠岩-海藻酸钙-活性炭复合材料对水中染料的高效吸附

IF 1.4 Q3 CHEMISTRY, MULTIDISCIPLINARY Physical Chemistry Research Pub Date : 2021-01-01 DOI:10.22036/PCR.2020.232973.1779
M. Chegeni, S. Etemadpour, M. Fekri
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引用次数: 4

摘要

为去除废水中的染料,采用简单方法制备了珍珠岩-海藻酸钙-活性炭(PCA)复合材料。通过FTIR、XRD、SEM和BET等技术对该复合材料进行了表征。PCA对亚甲基蓝(MB)和甲基橙(MO)等染料在1111和909 mg g-1水溶液中的吸附量较高。在ph值(3和8)、染料初始剂量(8和10 ppm)、吸附剂剂量(0.008和0.01)、时间(60 min)和温度(15-20℃)条件下,MO和MB的吸附效果最佳。制备的PCA对MB和MO的吸附符合拟二阶模型,符合Langmuir等温线。在最佳吸附条件下,获得了MB和MO的吸附收率。结果表明PCA是一种很好的染料吸附材料。所提出的基于绿色化学的制备方法与单一的原始材料应用相比,具有简单、经济、可重复使用的特点。
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The Perlite-calcium Alginate-activated Carbon Composite as an Efficient Adsorbent for the Removal of Dyes from Aqueous Solutions
To remove dyes from wastewater, the perlite-calcium alginate–activated carbon (PCA) composite was prepared by a simple method. This composite was characterized by FTIR, XRD, SEM, and BET techniques. A high capacity of PCA was observed for the adsorption of some dyes such as methylene blue (MB) and methyl orange (MO) from aqueous solutions (1111 and 909 mg g-1). The best results were achieved at pHs (3 and 8), dyes initial doses (8 and 10 ppm), adsorbent dose (0.008 and 0.01), time (60 min) and temperature (15-20 ⁰C) for MO and MB. The adsorption of MB and MO on the as-prepared PCA was matched by pseudo-second order model and corresponded to the Langmuir isotherm. Under optimum adsorption conditions, the yield of adsorption was obtained for MB and MO. Results indicated that PCA can be a good candidate for adsorption of dyes. The proposed green chemistry-based preparation method is simple, economical, and more reusable compared to the individual application of primary materials.
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来源期刊
Physical Chemistry Research
Physical Chemistry Research CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
2.70
自引率
8.30%
发文量
18
期刊介绍: The motivation for this new journal is the tremendous increasing of useful articles in the field of Physical Chemistry and the related subjects in recent years, and the need of communication between Physical Chemists, Physicists and Biophysicists. We attempt to establish this fruitful communication and quick publication. High quality original papers in English dealing with experimental, theoretical and applied research related to physics and chemistry are welcomed. This journal accepts your report for publication as a regular article, review, and Letter. Review articles discussing specific areas of physical chemistry of current chemical or physical importance are also published. Subjects of Interest: Thermodynamics, Statistical Mechanics, Statistical Thermodynamics, Molecular Spectroscopy, Quantum Chemistry, Computational Chemistry, Physical Chemistry of Life Sciences, Surface Chemistry, Catalysis, Physical Chemistry of Electrochemistry, Kinetics, Nanochemistry and Nanophysics, Liquid Crystals, Ionic Liquid, Photochemistry, Experimental article of Physical chemistry. Mathematical Chemistry.
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