火焰的熄灭

IF 0.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Quimica Nova Pub Date : 2023-02-01 DOI:10.21577/0100-4042.20230002
A. Pavão, G. Paiva, C. Bastos
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引用次数: 0

摘要

几个世纪以来,世界各地的观测者目睹了一种发光现象,但在现代已经看不到了,这表明它已经灭绝了。对这种消失的解释可以在描述为甲烷的冷却火焰中找到。与产生大量热量的传统火焰不同,火焰是一种通过化学发光过程而不产生热量的火焰。其特有的蓝色是由于释放的激发甲醛,这是在甲烷缓慢燃烧形成的。人们普遍认为这种现象是沼泽气体与空气中的氧气接触后的自燃,但对冷焰过程中所涉及的能量的分析表明,这种现象在本质上不是自发的。19世纪进行的实验表明,火炬被用来点燃火苗。放弃火而选择夜间照明可能是火神灭绝之谜的秘密所在。
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THE EXTINCTION OF THE IGNIS FATUUS
Ignis fatuus, a luminous phenomenon witnessed over the centuries by observers around the world, is no longer seen in modern times, suggesting that it is extinct. An explanation for this disappearance can be found in the description of ignis fatuus as a cool flame of methane. Unlike a conventional flame, which generates large amounts of heat, ignis fatuus is a flame that glows without heat through a chemiluminescence process. Its characteristic bluish color is due to the emission of excited formaldehyde, which is formed in the slow combustion of methane. It is generally accepted that the phenomenon is a spontaneous combustion of swamp gas in contact with the oxygen in air, but an analysis of the energies involved in the cool flame process indicates that the phenomenon is not spontaneous in nature. Experiments carried out in the 19th century show torches being used to ignite ignis fatuus. The abandonment of fire in favor of night lighting may hold the secret to this mystery of ignis fatuus’s extinction.
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来源期刊
Quimica Nova
Quimica Nova 化学-化学综合
CiteScore
1.60
自引率
12.50%
发文量
72
审稿时长
2-4 weeks
期刊介绍: Química Nova publishes in portuguese, spanish and english, original research articles, revisions, technical notes and articles about education in chemistry. All the manuscripts submitted to QN are evaluated by, at least, two reviewers (from Brazil and abroad) of recognized expertise in the field of chemistry involved in the manuscript. The Editorial Council can be eventually asked to review manuscripts. Editors are responsible for the final edition of QN.
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