after - ftir和uv-vis技术在生物柴油洗涤废水中甲醇分析中的应用

IF 0.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Quimica Nova Pub Date : 2023-08-28 DOI:10.21577/0100-4042.20230041
{"title":"after - ftir和uv-vis技术在生物柴油洗涤废水中甲醇分析中的应用","authors":"","doi":"10.21577/0100-4042.20230041","DOIUrl":null,"url":null,"abstract":"Methanol present in wastewater from the biodiesel industry can become an atmospheric pollutant and an environmental liability of effluents. This article proposes the development and performance evaluation of two spectroscopic methods, ATR-FTIR and UV-Vis, to identify and quantify methanol in aqueous media. The results of both ways exhibited remarkable linear detection, with a coefficient of determination (r2) > 0.99, wide working range, and relative standard deviation (RSD) < 12%. In the ATR-FTIR method, the detection and quantification limits were 0.064 and 0.128% m V-1, respectively. The UV-Vis method presented lower limits (0.005 and 0.008% m V-1, respectively). Finally, the methods were successfully applied to quickly and sensitively quantify the methanol present in wastewater from biodiesel-washing in a wide concentration range of 0.008-0.641% m V-1. Therefore, we evidenced the feasibility of spectroscopic methods in quality control for identifying and quantifying methanol in aqueous solution, with potential for application in biodiesel production industries and research laboratories. Mainly by ATR-FTIR, in the region of 1300-900 cm-1, as it proved to be more environmentally friendly, faster, and cheaper than the GC-FID method.","PeriodicalId":49641,"journal":{"name":"Quimica Nova","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"ATR-FTIR AND UV-VIS AS TECHNIQUES FOR METHANOL ANALYSIS IN BIODIESEL-WASHING WASTEWATER\",\"authors\":\"\",\"doi\":\"10.21577/0100-4042.20230041\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Methanol present in wastewater from the biodiesel industry can become an atmospheric pollutant and an environmental liability of effluents. This article proposes the development and performance evaluation of two spectroscopic methods, ATR-FTIR and UV-Vis, to identify and quantify methanol in aqueous media. The results of both ways exhibited remarkable linear detection, with a coefficient of determination (r2) > 0.99, wide working range, and relative standard deviation (RSD) < 12%. In the ATR-FTIR method, the detection and quantification limits were 0.064 and 0.128% m V-1, respectively. The UV-Vis method presented lower limits (0.005 and 0.008% m V-1, respectively). Finally, the methods were successfully applied to quickly and sensitively quantify the methanol present in wastewater from biodiesel-washing in a wide concentration range of 0.008-0.641% m V-1. Therefore, we evidenced the feasibility of spectroscopic methods in quality control for identifying and quantifying methanol in aqueous solution, with potential for application in biodiesel production industries and research laboratories. Mainly by ATR-FTIR, in the region of 1300-900 cm-1, as it proved to be more environmentally friendly, faster, and cheaper than the GC-FID method.\",\"PeriodicalId\":49641,\"journal\":{\"name\":\"Quimica Nova\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2023-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Quimica Nova\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.21577/0100-4042.20230041\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Quimica Nova","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.21577/0100-4042.20230041","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

生物柴油工业废水中存在的甲醇可能成为大气污染物和废水的环境负担。本文提出了ATR-FTIR和UV-Vis两种光谱方法的发展和性能评价,用于鉴别和定量水介质中的甲醇。两种方法均具有良好的线性检测效果,检测系数(r2)均为0.99,工作范围宽,相对标准偏差(RSD) < 12%。在ATR-FTIR方法中,检测限和定量限分别为0.064和0.128% m V-1。紫外可见法的下限分别为0.005 m V-1和0.008% m V-1。最后,这些方法成功地用于快速、灵敏地定量生物柴油洗涤废水中存在的甲醇,浓度范围为0.008-0.641% m V-1。因此,我们证明了光谱方法在鉴别和定量水溶液中甲醇的质量控制中的可行性,具有应用于生物柴油生产行业和研究实验室的潜力。主要是通过ATR-FTIR,在1300-900 cm-1范围内,因为它被证明比GC-FID方法更环保,更快,更便宜。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
ATR-FTIR AND UV-VIS AS TECHNIQUES FOR METHANOL ANALYSIS IN BIODIESEL-WASHING WASTEWATER
Methanol present in wastewater from the biodiesel industry can become an atmospheric pollutant and an environmental liability of effluents. This article proposes the development and performance evaluation of two spectroscopic methods, ATR-FTIR and UV-Vis, to identify and quantify methanol in aqueous media. The results of both ways exhibited remarkable linear detection, with a coefficient of determination (r2) > 0.99, wide working range, and relative standard deviation (RSD) < 12%. In the ATR-FTIR method, the detection and quantification limits were 0.064 and 0.128% m V-1, respectively. The UV-Vis method presented lower limits (0.005 and 0.008% m V-1, respectively). Finally, the methods were successfully applied to quickly and sensitively quantify the methanol present in wastewater from biodiesel-washing in a wide concentration range of 0.008-0.641% m V-1. Therefore, we evidenced the feasibility of spectroscopic methods in quality control for identifying and quantifying methanol in aqueous solution, with potential for application in biodiesel production industries and research laboratories. Mainly by ATR-FTIR, in the region of 1300-900 cm-1, as it proved to be more environmentally friendly, faster, and cheaper than the GC-FID method.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Quimica Nova
Quimica Nova 化学-化学综合
CiteScore
1.60
自引率
12.50%
发文量
72
审稿时长
2-4 weeks
期刊介绍: Química Nova publishes in portuguese, spanish and english, original research articles, revisions, technical notes and articles about education in chemistry. All the manuscripts submitted to QN are evaluated by, at least, two reviewers (from Brazil and abroad) of recognized expertise in the field of chemistry involved in the manuscript. The Editorial Council can be eventually asked to review manuscripts. Editors are responsible for the final edition of QN.
期刊最新文献
ATIVAÇÃO DE COMPOSTO ORGÂNICO COM ÁCIDO FOSFÓRICO E OS EFEITOS NA ADSORÇÃO DE Pb E Cd UTILIZAÇÃO DE MODELOS IN SILICO PARA AVALIAÇÃO DA TOXICIDADE DE RESÍDUOS DE AGROTÓXICOS, FÁRMACOS E METABÓLITOS EM ÁGUAS NATURAIS RGB-LED-PHOTOMETER AND THE DIGITAL IMAGE-BASED METHOD USING A SMARTPHONE FOR CHEMISTRY AND PHYSICS TEACHING INTELIGÊNCIA ARTIFICIAL E ENSINO DE QUÍMICA: UMA ANÁLISE PROPEDÊUTICA DO CHATGPT NA DEFINIÇÃO DE CONCEITOS QUÍMICOS A COMPUTATIONAL STUDY OF THE ANTIOXIDANT POWER OF EUGENOL COMPARED TO VITAMIN C
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1