聚合物和弹性体暴露于氯化水中的降解研究综述

N. Samarth, P. Mahanwar
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引用次数: 12

摘要

在水工业中,氯主要用作消毒剂。据报道,饮用水中作为消毒剂存在的氯可以减少接触高分子材料的寿命。这种情况发生在聚合物管道中,现在在管道和饮用水分配系统的其他部分非常普遍。50多年来,聚合物和弹性体材料已广泛应用于饮用水分配系统。聚合物和弹性材料已经成功地应用于橡胶垫片、阀门、消火栓和配件等各种应用中。聚合物和弹性体的降解速度比预期的要快,这会产生服务问题,使公用事业公司难以制定经济有效的预防性维护计划,并对客户关系产生负面影响。本文对聚合物和弹性体的选择及其在氯化水中的性能预测提供了一些见解。讨论了聚合物弹性体在含氯环境下的降解机理,以及聚合物弹性体在不同条件和参数下的使用寿命模型。通过红外分光光度法、拉伸测试、熔体流变法和接枝氯滴定法研究了408C和408C的持续时间长达1200 h。红外光谱显示羰基生长表明DOC诱导PE氧化。流变学显示链断裂的优势,可能与氢过氧化氢分解有关。拉伸测试显示,当重量平均摩尔质量MW接近70 kg mol21的临界值时,发生了脆化过程,这与之前PE热氧化的研究结果一致。
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Degradation of Polymer & Elastomer Exposed to Chlorinated Water—A Review
In water industry, the chlorine is mostly used as a disinfectant agent. The chlorine present in potable water as a disinfectant has been reported to reduce the lifetime of contact polymeric material. This occurs in polymer pipes and it is now very common in plumbing and other parts of the drinking water distribution system. For more than 50 years, Polymer & Elastomeric materials have been used ubiquitously in drinking water distribution systems. Polymer & Elastomeric materials have successfully been used in a variety of applications ranging from rubber gaskets, to valves, to hydrants, to fittings. Polymer & Elastomers that degrade more quickly than expected create service problems, make it difficult for utilities to cost efficient plan preventive maintenance programs, and negatively affect customer relations. This review paper gives an insight idea to a reader about the selection of proper polymer & elastomer and predicting its performance in chlorinated water. Also the mechanism of degradation of Polymer & elastomer in chlorine environment and some model of life expectancy of in-service of Polymer & elastomer in various conditions and parameter in chlorinated water were discussed. and 408C for durations up to 1200 h has been studied by IR spectrophotometry, tensile testing, melt rheometry, and grafted chlorine titration. IR revealed a carbonyl growth indicating that DOC induces PE oxidation. Rheometry revealed the predominance of chain scissions, presumably linked to hydroperoxide decomposition. Tensile testing revealed an embrittlement process when the weight average molar mass MW approaches a critical value of 70 kg mol21, which agrees with a previous study of PE thermooxidation.
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来源期刊
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