含铝硼闪光粉烟花渣的评价

Q4 Environmental Science Pollution Research Pub Date : 2023-01-01 DOI:10.53550/pr.2023.v42i01.003
A. AZHAGURAJAN, M. K. Marichelvam, L. PRAKASH
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引用次数: 0

摘要

本文报道了由不同数量的铝(Al)和硼(B)组成的闪粉混合物与硝酸钾(KNO3)和硫(S)等含能物质点燃后得到的残留物的特征。通过FESEM-EDX、FTIR、STA (TGA/DSC)和ICP光谱仪表征了燃烧后收集的颗粒物的性质。FTIR光谱分析显示存在多种金属氧化物,如K2 S和K2 SO4。用硼代替铝后,残渣中较多碱性的K2 S转化为中性的K2 SO4。FESEM和EDX证实了Al, B, K, S, O等元素的存在,燃烧后形成的颗粒尺寸约为400 nm。用ICP谱仪对残渣进行分析,证实硼逐渐取代铝。硼混合烟花混合物在点火时产生优异的性能,产生的残留物不具有任何危害性。
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EVALUATION OF FIREWORKS RESIDUE OBTAINED FROM THE FLASH POWDER CONTAINING ALUMINIUM AND BORON
Herein, we report the characteristics of residues obtained after igniting the flash powder mixture consisting of varying amounts of Aluminium (Al) and Boron (B) with other energetic materials like potassium nitrate (KNO3 ) and sulphur (S). The nature of particulate matter collected after combustion was characterized through FESEM-EDX, FTIR, STA (TGA/DSC) and ICP spectrometer. FTIR spectra analysis reveals about the presence of various metal oxides, K2 S and K2 SO4 . On replacing aluminum by boron, more alkaline K2 S present in the residue was converted into the neutral K2 SO4 . FESEM with EDX confirm the presence of the elements like Al, B, K, S, O, etc., and the size of the particles formed after combustion is about 400 nm. The gradual replacement of aluminum by boron is substantiated from the analysis of residue through ICP Spectrometer. Boron blended fireworks mixture on ignition produces excellent performances and the residues generated do not have any hazardous nature.
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来源期刊
Pollution Research
Pollution Research Environmental Science-Water Science and Technology
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期刊介绍: POLLUTION RESEARCH is one of the leading enviromental journals in world and is widely subscribed in India and abroad by Institutions and Individuals in Industry, Research and Govt. Departments.
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