芳基磺酰基酞酰亚胺的合成及其与几种胺在乙腈中的反应

S. Ozturk, H. Kutuk
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引用次数: 2

摘要

本研究合成了几种N-(对取代芳基磺酰)邻苯二甲酸亚胺(1a-e)。然后对合成的化合物在乙腈中与t-丁胺、二乙胺、环己胺和反式-1,2-二氨基环己烷的取代反应进行了研究。为确定反应机理,以取代基效应、激活熵和亲核试剂效应为标准。
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The Synthesis of Arylsulfonylphthalimides and Their Reactions with Several Amines in Acetonitrile
In this study, several N-(p-substituted-arylsulfonyl)phthalimides (1a-e) were synthesized. The synthesized compounds were then examined with respect to their substitution reactions with t-butylamine, diethylamine, cyclohexylamine, and trans-1,2-diaminocyclohexane in acetonitrile. In order to determine the mechanism, substituent effect, activation entropy, and nucleophile effect were used as criteria.
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