Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li and Feng Yu
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Ba3(BS3)(PS4): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS3] units†
The first alkaline-earth metal thioborate–thiophosphate Ba3(BS3)(PS4) was designed from Ba3(BO3)(PO4) by S–O substitution and fabricated experimentally. The [BS3] pseudo-layers formed in the structure contribute to the strong optical anisotropy and a large birefringence of ∼0.11 at 1064 nm. The results enrich the structural and chemical diversity of chalcogenides.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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