合成硅酸铝包覆二氧化钛光催化剂功能填料的表征

IF 2.3 4区 材料科学 Q2 Chemistry Journal of Coatings Technology and Research Pub Date : 2023-07-05 DOI:10.1007/s11998-023-00794-3
Fumihiko Ohashi
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引用次数: 0

摘要

以不同化学成分的硅酸铝前驱体和二氧化钛悬浮液为原料,通过水热反应合成了非晶态硅酸铝包覆二氧化钛纳米复合材料。AS-T纳米复合材料的粒径分布以1.0 ~ 2.0 μm为中心,比表面积在138 ~ 209 m2/g之间。水蒸气吸附等温线表明,高Si/Al比的as - t纳米复合材料具有较高的亲水性,最大吸水率接近40 wt%。在亚甲基蓝光催化降解试验中,具有较高Si/Al比的AS-T纳米复合材料的光降解性比商用二氧化钛高得多,在紫外线照射30分钟后,亚甲基蓝的降解率高达92.7%。可能的机制是暴露在硅酸铝表面的Si(Al) -OH和/或Si -OH - Al的分布状态影响了表面对亚甲基蓝的吸附,从而显著提高了光降解性能。研究结果表明,as - t纳米复合材料具有作为涂料填料的潜力。
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Characterization of synthetic aluminum silicate-coated titanium dioxide photocatalysts as a functional filler

Synthetic amorphous aluminum silicates-coated titanium dioxides (AS–T nanocomposites) were synthesized by a hydrothermal reaction of aluminum silicate precursors with various chemical compositions and titanium dioxide suspensions. AS–T nanocomposites showed narrow particle size distributions centered between 1.0 and 2.0 μm and their specific surface areas were ranging from 138 to 209 m2/g. Water vapor adsorption isotherms revealed that AS–T nanocomposites with higher Si/Al ratios exhibited high hydrophilicity, as the maximum water adsorption rate reached almost 40 wt%. In methylene blue photocatalytic degradation tests, AS–T nanocomposites with higher Si/Al ratios showed much higher photodegradability than a commercial titanium dioxide, degrading up to 92.7% of methylene blue after 30 min of UV irradiation. A possible mechanism is that a distribution state of Si(Al)–OH and/or Si–OH–Al exposed on the aluminum silicate surface influenced the methylene blue adsorption to the surface, which significantly improved the photodegradation performance. The results of this study indicate that AS–T nanocomposites have the potential to be used as fillers in paints.

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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research CHEMISTRY, APPLIED-MATERIALS SCIENCE, COATINGS & FILMS
CiteScore
4.40
自引率
8.70%
发文量
0
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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