破裂太阳能电池的场和加速老化

IF 2.5 3区 工程技术 Q3 ENERGY & FUELS IEEE Journal of Photovoltaics Pub Date : 2023-09-19 DOI:10.1109/JPHOTOV.2023.3309933
Michael G. Deceglie;Timothy J Silverman;Ethan Young;William B. Hobbs;Cara Libby
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引用次数: 0

摘要

由于机械应力(如粗暴处理或冰雹),否则完整的光伏模块中的硅太阳能电池可能会形成裂纹。这些裂纹对功率的直接影响可以很容易地测量,但从加速测试中也可以看出,裂纹可能会随着时间的推移而恶化。然而,目前尚不清楚如何预测未来因电池破裂而导致的电场退化程度,这需要经过校准的加速测试。我们描述了这种测试的进展。特别是,我们报道了电池破裂的模块在户外老化近两年的情况。我们发现,在21个月的时间里,具有破裂细胞的模块在现场的降解率比未破裂的模块平均高0.5%。我们还对具有多温度电致发光的模块进行了表征,并发现降解与电隔离的细胞碎片有关。我们将户外风化与两种类型的加速试验进行了比较:热循环和一种新的加速试验,即动态机械加速度(DMX)。DMX可以在大约10 Hz的频率和<200的压力下应用数千个压力循环 Pa,这与模块在室外经历的风驱动压力循环有关。我们发现,设计用于再现场的累积温度变化的热循环高估了场退化,并可能激发非单元裂纹退化。DMX的结果很有希望,通过不到一小时的测试,重现了21个月来在户外观察到的类似降解水平。
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Field and Accelerated Aging of Cracked Solar Cells
Cracks can form in silicon solar cells in an otherwise intact photovoltaic module due to mechanical stresses such as rough handling or hail. The immediate impact on power due to these cracks can be readily measured, but it is also known from accelerated testing that the cracks can worsen over time. However, it is not clear how to predict the extent of future field degradation due to cracked cells, which requires a calibrated accelerated test. We describe progress toward such a test. In particular, we report on the outdoor aging of modules with cracked cells for nearly two years. We find that modules with cracked cells degraded in the field an average of 0.5% absolute more than uncracked modules over a period of 21 months. We also characterize the modules with multitemperature electroluminescence and find that the degradation is associated with cell fragments that become electrically isolated. We compare the weathering outdoors with the two types of accelerated tests: thermal cycling and a novel accelerated test, dynamic mechanical acceleration (DMX). DMX can apply thousands of pressure cycles at a frequency of approximately 10 Hz and pressures <200 Pa, which are relevant to the wind-driven pressure cycles experienced by modules outdoors. We find that the thermal cycles designed to reproduce the cumulative temperature change from the field overestimate field degradation and can excite noncell-crack degradation. DMX results were promising, reproducing degradation levels similar to those observed outdoors over 21 months with a test that can be performed in less than an hour.
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来源期刊
IEEE Journal of Photovoltaics
IEEE Journal of Photovoltaics ENERGY & FUELS-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
7.00
自引率
10.00%
发文量
206
期刊介绍: The IEEE Journal of Photovoltaics is a peer-reviewed, archival publication reporting original and significant research results that advance the field of photovoltaics (PV). The PV field is diverse in its science base ranging from semiconductor and PV device physics to optics and the materials sciences. The journal publishes articles that connect this science base to PV science and technology. The intent is to publish original research results that are of primary interest to the photovoltaic specialist. The scope of the IEEE J. Photovoltaics incorporates: fundamentals and new concepts of PV conversion, including those based on nanostructured materials, low-dimensional physics, multiple charge generation, up/down converters, thermophotovoltaics, hot-carrier effects, plasmonics, metamorphic materials, luminescent concentrators, and rectennas; Si-based PV, including new cell designs, crystalline and non-crystalline Si, passivation, characterization and Si crystal growth; polycrystalline, amorphous and crystalline thin-film solar cell materials, including PV structures and solar cells based on II-VI, chalcopyrite, Si and other thin film absorbers; III-V PV materials, heterostructures, multijunction devices and concentrator PV; optics for light trapping, reflection control and concentration; organic PV including polymer, hybrid and dye sensitized solar cells; space PV including cell materials and PV devices, defects and reliability, environmental effects and protective materials; PV modeling and characterization methods; and other aspects of PV, including modules, power conditioning, inverters, balance-of-systems components, monitoring, analyses and simulations, and supporting PV module standards and measurements. Tutorial and review papers on these subjects are also published and occasionally special issues are published to treat particular areas in more depth and breadth.
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