{"title":"新型anderson型多金属氧酸盐的合成与表征:[M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu)x = 1, 2)","authors":"Hülya Avcı Özbek","doi":"10.18596/jotcsa.1215066","DOIUrl":null,"url":null,"abstract":"Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"61 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)\",\"authors\":\"Hülya Avcı Özbek\",\"doi\":\"10.18596/jotcsa.1215066\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.\",\"PeriodicalId\":17299,\"journal\":{\"name\":\"Journal of the Turkish Chemical Society Section A: Chemistry\",\"volume\":\"61 3\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Turkish Chemical Society Section A: Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18596/jotcsa.1215066\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Turkish Chemical Society Section A: Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18596/jotcsa.1215066","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)
Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.
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