用于燃料电池的cuspidin型固体氧化物

N. Cioateră
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摘要

采用改进的Pechini法在较低的温度下合成了具有La4(Ti2O8)O2和La4(Ti1.5Al0.5O8-δ)O2的cuspidin型固体氧化物。用TG/DSC技术评价了它们的热行为。还原-氧化过程在加热和冷却阶段均得到证实,其幅度取决于气体气氛和样品成分。
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Cuspidine-type Solid Oxides for Fuel Cell applications
Cuspidine-type solid oxides having the compositions La4(Ti2O8)O2 and La4(Ti1.5Al0.5O8-δ)O2 were synthesized using a modified Pechini method at much lower temperature than the one corresponding to the state of the art ceramic method. Their thermal behaviour was evaluated using TG/DSC techniques. Reduction-oxidation processes were evidenced on both heating and cooling stages, their amplitude depending on gas atmosphere and sample composition.
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