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Photocatalytic membrane system: Obtaining procedure and environmental application 光催化膜系统:制备过程及环境应用
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400773
C. Orbeci, G. Nechifor, I. Untea
This study reveals the synthesis of a membrane system by a simple and efficient procedure. The conditions used for preparing a membrane system to a substrate have a great effect on its performance. The determination of a suitable immobilisation procedure for specific application becomes complicated with the methods developed over the years. A hybrid coating of fiberglass served as substrate to obtain a photocatalytic system. The working procedure is based on the immersion of fiberglass in suspension consisting of sodium silicate solution and titanium dioxide. The new synthesised membrane system was characterized using X-ray spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. The present study is focused on the procedure for obtaining new materials for environmental applications and performance evaluation of membrane system in advanced oxidation processes. The photocatalytic activity of the membrane system was evaluated through the oxidation process of organic compounds from wastewater. A synthetic solution by 4-chlorophenol was used as test substance. Removal of phenols compounds from wastewater is extremely important from an environmental perspective.
本研究揭示了一种简单有效的膜系统合成方法。制备膜系统的条件对其性能有很大影响。随着多年来开发的方法,确定适合特定应用的固定程序变得复杂。玻璃纤维的杂化涂层作为衬底,得到光催化体系。工序是将玻璃纤维浸泡在由硅酸钠溶液和二氧化钛组成的悬浮液中。利用x射线光谱、扫描电镜和能量色散x射线光谱对新合成的膜体系进行了表征。本文主要研究了环境应用新材料的制备方法和膜系统在高级氧化过程中的性能评价。通过对废水中有机物的氧化过程,评价了膜系统的光催化活性。以4-氯酚合成溶液为试验物质。从环境的角度来看,从废水中去除酚类化合物是极其重要的。
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引用次数: 0
Study of piezoelectrycity in structures based on nanofibrous ZnO layers and polysilane 基于纳米纤维ZnO层和聚硅烷结构的压电性研究
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400780
L. Ghimpu, V. Cojocaru, M. Soroceanu, L. Săcărescu, A. Katashev, V. Harabagiu, I. Tiginyanu
Zinc oxide films were deposited by method rf magnetron sputtering in a mixed environment of oxygen and argon on two types of substrates, glass and silicon substrates with different orientations, by varying the deposition parameters in order to obtain high-quality ZnO nanostructured layers. An atomic force microscope was used to measure the piezoelectricity in nanofibrous layers and poly [methyl (H) silane]. The interaction between the type of semiconductor/poly[methyl(H)silane] and the applied electric field has proved that the given structures are piezoelectric materials useful for fabrication of optoelectronic devices.
采用射频磁控溅射的方法,在氧气和氩气混合环境下,在不同取向的玻璃基片和硅基片上沉积氧化锌薄膜,通过改变沉积参数,获得高质量的氧化锌纳米结构层。利用原子力显微镜测量了纳米纤维层和聚甲基硅烷的压电性。半导体/聚[甲基(H)硅烷]类型与外加电场之间的相互作用证明了给定结构是可用于制造光电器件的压电材料。
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引用次数: 0
On magnetic nanoparticles detection using planar Hall effect sensors 基于平面霍尔效应传感器的磁性纳米颗粒检测研究
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400774
M. Volmer, M. Avram
In this paper we present aspects concerning magnetic nanoparticles detection using a planar Hall effect magnetometer, disk-shaped of 1mm diameter, build from a single Permalloy layer, 20 nm thick, deposited on oxidized Si substrate. This device allows us to measure the stray magnetic field generated by superparamagnetic beads which are magnetized by an external field. During the experiments we found strong sensor signal dependence, both in shape and magnitude, with the particles at different positions. The results are explained by means of micromagnetic simulations were magnetostatic interactions between magnetic nanobeads and sensor are clearly highlighted.
在本文中,我们介绍了使用平面霍尔效应磁力计检测磁性纳米颗粒的方面,该磁力计直径为1mm的圆盘状,由沉积在氧化硅衬底上的20 nm厚的单一坡莫合金层构建而成。该装置使我们能够测量被外场磁化的超顺磁珠产生的杂散磁场。在实验中,我们发现在不同位置的粒子在形状和大小上都有很强的传感器信号依赖性。结果通过微磁模拟得到了解释,磁性纳米珠与传感器之间的静磁相互作用得到了明显的强调。
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引用次数: 0
Porous silicon decorated metallic nanoparticles for growing vertically aligned carbon nanotubes 用于生长垂直排列碳纳米管的多孔硅修饰金属纳米颗粒
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400692
L. Veca, F. Craciunoiu, M. Kusko, M. Danila, A. Dinescu
Carbon nanotubes have been envisioned as promising functional materials in nanoelectronics and electron field emitters. All these applications require that the CNT are highly oriented. There are many studies to improve the growth process but only few research studies have investigated new methods to deposit metallic nanoparticles on the porous silicon. Thus this paper is aiming at synthesizing metallic nanoparticles on top of porous silicon.
碳纳米管是纳米电子学和电子场发射材料中很有前途的功能材料。所有这些应用都要求碳纳米管具有高度的定向性。在多孔硅表面沉积金属纳米颗粒的新方法研究较少,但对其生长工艺的改进研究较多。因此,本文的目标是在多孔硅表面合成金属纳米颗粒。
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引用次数: 1
Nonlinear plasmonic couplers 非线性等离子体耦合器
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400673
C. Kusko
In this work we have numerically investigated by employing the finite difference time domain (FDTD) method the coupling between two metal-dielectric-metal (MDM) plasmonic waveguides supporting symmetric forward propagating fundamental modes, one of them presenting a Kerr non-linearity. A coupling analysis is performed in order to investigate the all - optical switching properties of this directional coupler. This analysis was performed for optimization of this coupler in terms of length, modal characteristics of the waveguides as well as the input power.
在这项工作中,我们采用时域有限差分(FDTD)方法对支持对称前向传播基模的两个金属-介电-金属(MDM)等离子体波导之间的耦合进行了数值研究,其中一个呈现克尔非线性。为了研究这种定向耦合器的全光开关特性,进行了耦合分析。对该耦合器的长度、波导模态特性以及输入功率进行了优化分析。
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引用次数: 1
Distributed feedback lasers with photon-photon-resonance-enhanced modulation bandwidth 光子-光子共振增强调制带宽的分布式反馈激光器
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400678
M. Dumitrescu, A. Laakso, J. Viheriala, T. Uusitalo, M. Kamp, P. Uusimaa
Multi-section distributed-feedback lasers with surface gratings have been fabricated without re-growth by employing ultraviolet nanoimprint lithography. High-frequency photon-photon resonance was exploited to extend the direct modulation bandwidth beyond the conventional limits set by the carrier-photon resonance.
利用紫外纳米压印光刻技术制备了具有表面光栅的多截面分布反馈激光器,实现了激光器的无再生。利用高频光子-光子共振将直接调制带宽扩展到载波-光子共振所设定的常规限制之外。
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引用次数: 8
Modelling 2DEG charges in AlGaN/GaN heterostructures 模拟AlGaN/GaN异质结构中的2DEG电荷
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400760
G. Longobardi, F. Udrea, S. Sque, J. Croon, F. Hurkx, E. Napoli, J. Sonsky
In this paper we compare different approaches to calculating the charge density in the 2DEG layer of AlGaN/GaN HEMTs. The methods used are (i) analytical theory implemented in MATLAB, (ii) finite-element analysis using semiconductor TCAD software that implements only the Poisson and continuity equations, and (iii) 1D software that solves the Poisson and Schrödinger equations self-consistently. By using the 1D Poisson-Schrödinger solver, we highlight the consequences of neglecting the Schrödinger equation. We conclude that the TCAD simulator predicts with a reasonable level of accuracy the electron density in the 2DEG layer for both a conventional HEMT structure and one featuring an extra GaN cap layer. In addition, while the sheet charge density is not significantly affected by including Schrödinger, its confinement in the channel is found to be modified.
在本文中,我们比较了计算AlGaN/GaN hemt 2DEG层电荷密度的不同方法。使用的方法是(i)在MATLAB中实现的分析理论,(ii)使用半导体TCAD软件进行的有限元分析,该软件仅实现泊松方程和连续性方程,以及(iii)自一致地解决泊松方程和Schrödinger方程的1D软件。通过使用一维Poisson-Schrödinger求解器,我们强调了忽略Schrödinger方程的后果。我们得出的结论是,TCAD模拟器以合理的精度预测了传统HEMT结构和具有额外GaN帽层的HEMT结构的2DEG层中的电子密度。此外,虽然加入Schrödinger对薄片电荷密度没有显著影响,但发现其在通道中的约束被改变。
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引用次数: 9
Three dimensional heteroepitaxy: A new path for monolithically integrating mismatched materials with silicon 三维异质外延:不匹配材料与硅单片集成的新途径
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400698
C. Falub, T. Kreiliger, A. Taboada, F. Isa, D. Chrastina, G. Isella, E. Muller, M. Meduňa, R. Bergamaschini, A. Marzegalli, E. Bonera, F. Pezzoli, L. Miglio, P. Niedermann, A. Neels, A. Pezous, R. Kaufmann, A. Dommann, H. von Kanel
In the quest for a Ge x-ray detector mono-lithically integrated onto a Si-CMOS chip we developed a novel method for combining dissimilar materials that may provide a solution to the main problems of heteroepitaxy, e.g. high threading dislocation densities, wafer bowing and cracks. It consists of replacing the conventional continuous layers by space-filling arrays of strain- and defect-free Ge crystals, the width, height and shape of which are controlled by tuning epitaxial growth onto micrometer-sized features deeply etched into Si-substrates. Heterojunctions formed between the Ge-crystals and the Si-substrate exhibit the required rectifying diode behavior with low dark currents (<;1 mA/cm2).
为了将锗x射线探测器单片集成到Si-CMOS芯片上,我们开发了一种结合不同材料的新方法,可以解决异质外延的主要问题,例如高螺纹位错密度,晶圆弯曲和裂纹。它包括用无应变和无缺陷的Ge晶体的空间填充阵列取代传统的连续层,其宽度,高度和形状是通过调谐外延生长到微米尺寸的特征上来控制的,这些特征被深深蚀刻在si衬底上。ge晶体和si衬底之间形成的异质结在低暗电流(< 1 mA/cm2)下表现出所需的整流二极管行为。
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引用次数: 2
A new small size ring coupler based on fully distributed Composite Right/Left-Handed structures 一种基于全分布左/右复合结构的小尺寸环形耦合器
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400651
S. Simion
A new topology of small size ring coupler is proposed. It consists of fully distributed balanced CRLH (Composite Right/Left-Handed) based phase shifters, designed for a frequency which is significantly greater than the coupler operating frequency. Firstly, the equivalent circuit of the ring coupler consisting of ideal transmission lines is designed for operating frequency chosen at 1.8 GHz, and then this circuit is analysed numerically. The coupler layout is also designed and numerically analysed using a 3D electromagnetic simulator. The proposed ring coupler has about 50% smaller area comparing to the conventional configuration, this being an advantage for low operating frequency. Also, comparing to other small size ring coupler topologies reported in the literature, the proposed coupler may be fabricated using standard one mask technological process, as well as for the conventional ring coupler configuration.
提出了一种新的小尺寸环形耦合器拓扑结构。它由完全分布平衡的CRLH(复合右/左)相移器组成,设计用于明显大于耦合器工作频率的频率。首先设计了理想传输线组成的环形耦合器的等效电路,工作频率选择在1.8 GHz,然后对该电路进行了数值分析。利用三维电磁模拟器对耦合器的布局进行了设计和数值分析。与传统配置相比,所提出的环形耦合器的面积约小50%,这是低工作频率的优势。此外,与文献中报道的其他小尺寸环形耦合器拓扑结构相比,所提出的耦合器可以使用标准的单掩模工艺制造,也可以用于传统的环形耦合器结构。
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引用次数: 3
Mesoporous ceria-zirconia solid solutions as oxygen gas sensing material using high temperature hot plates 介孔氧化锆固溶体作为高温热板氧敏材料
Pub Date : 2012-10-01 DOI: 10.1109/SMICND.2012.6400786
S. A. Ghom, T. Andreu, C. Zamani, J. Morante
Mesoporous ceria and ceria-zirconia solid solutions have been synthesized following a route based on the use of silica hard template. Two different structures have been selected, one based on a three dimensional gyroidal structure, named KIT6, and other based on a two dimensional layered structure named SBA15. The presence of zirconium in the ceria sub lattice enhances the capability to transform Ce+4 to Ce+3 such as it is proved from the thermogravimetry measurements that show a large increase of the oxygen storage capacity. Ce(1-x)ZrxO2 solid solutions prepared making replicas of previously synthesized mesoporous silica have been characterized and tested under different oxygen-containing atmospheres at sensing temperatures above 500oC with oxygen variation between 1% to 100% of oxygen. This binary compound oxide present a variation of its electrical conductivity with the oxygen partial pressure that follow a potential law R=Ro[O2]1/n with n = 4 corroborating that the sensing mechanism is dominated by electronic conductivity processes related to the contribution of the Ce+3. Therefore, these high stable mesoporous materials with high active surface become a promising candidate as oxygen sensing materials for gas sensing hotplate platforms.
采用基于二氧化硅硬模板的方法合成了介孔二氧化铈和二氧化铈固溶体。选择了两种不同的结构,一种是基于三维陀螺仪结构,命名为KIT6,另一种是基于二维分层结构,命名为SBA15。锆的存在增强了铈亚晶格中Ce+4向Ce+3转化的能力,热重测量结果证明了这一点,表明储氧容量大大增加。制备的Ce(1-x)ZrxO2固溶体仿造了先前合成的介孔二氧化硅,在不同的含氧气氛下进行了表征和测试,感应温度在500℃以上,氧气含量在1%到100%之间变化。该二元化合物氧化物的电导率随氧分压的变化遵循R=Ro[O2]1/n, n = 4的电位规律,证实了感应机制主要由与Ce+3贡献相关的电子电导率过程主导。因此,这些具有高活性表面的高稳定性介孔材料成为气敏热板平台氧敏材料的理想候选材料。
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引用次数: 2
期刊
CAS 2012 (International Semiconductor Conference)
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