基于高密度和低密度聚乙烯混合物的复合材料的热机械性能

F. Mustafayeva, N. T. Kahramanov
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摘要

本文介绍了聚合物组分配比——高密度聚乙烯和低密度聚乙烯对热工性能变化规律的影响。在不同温度和0.5 kg/cm2的恒定载荷下测量变形。低密度聚乙烯的浓度从10%到100%不等。根据测试温度的不同,记录了两种物理状态:固体状态和粘流状态。研究发现,随着聚合物混合物组成中低密度聚乙烯浓度的升高,软化态转变温度和粘流态转变温度下降。差热分析曲线表明,在低浓度的高密度聚乙烯下,聚合物体系形成两相体系。以氢氧化铝和高低密度聚乙烯的混合物为基础的复合材料的研究表明,软化温度和粘流温度呈波浪状变化。
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THERMOMECHANICAL PROPERTIES OF COMPOSITE MATERIALS BASED ON MIXTURES OF HIGH AND LOW DENSITY POLYETHYLENES
The results of the research into the influence of polymer components ratio - high density polyethylene and low density polyethylene, into the regularity of changes in thermomechanical properties are presented. The deformation was measured at varying temperatures and at a constant load of 0.5 kg/cm2 . The concentration of low density polyethylene varied from 10 to 100 wt%. Depending upon the test temperature, two physical states were recorded: solid and viscous-flow. It found that as the concentration of low-density polyethylene in the composition of the polymer mixture rose, the transition temperature in the softened state and the transition temperature in the viscous-flow state dropped. The differential thermal analysis curves showed that at low concentrations of high density polyethylene, two-phase systems were formed in the polymer system. The study of composites based on aluminum hydroxide and a mixture of high and low density polyethylene revealed a wave-like change in softening and viscous-flow temperatures.
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