1-(4-磺酸)丁基氢硫酸吡啶催化的瑞士白草油基生物柴油

A. Zhang, Changzhu Li
{"title":"1-(4-磺酸)丁基氢硫酸吡啶催化的瑞士白草油基生物柴油","authors":"A. Zhang, Changzhu Li","doi":"10.1109/ICMREE.2013.6893682","DOIUrl":null,"url":null,"abstract":"In the present work, biodiesel feedstock from Swida wilsoniana fruit oil was catalyzed by BrΦnsted acidic ionic liquid of 1-(4-sulfonic acid)butyl-pyridinium hydrosulfate. The ionic liquid was synthesized with acetone as solvent. The functions of ionic liquid catalyst dosage, mole ratio of methanol to Swida wilsoniana oil, reaction temperature and reaction time on process and ionic liquid properties were investigated. The transesterification characteristics were improved by that ionic liquid. The optimal transesterification conditions were shown as n(methanol)/n (Swida wilsoniana oil) 12, m(catalyst)/m(Swida wilsoniana oil) 0.06, reaction temperature 160 °C and reaction time 6 h, transesterification rate reach 94.0%. The ionic liquid was stable, which can be reused more than six times. Main quality indexes of biodiesel prepared come up to the biodiesel standard of GB/T20828-2007 in China.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"18 1","pages":"355-359"},"PeriodicalIF":0.0000,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Swida wilsoniana oil based biodiesel catalyzed by 1-(4-sulfonic acid) butyl-pyridinium hydrosulfate\",\"authors\":\"A. Zhang, Changzhu Li\",\"doi\":\"10.1109/ICMREE.2013.6893682\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the present work, biodiesel feedstock from Swida wilsoniana fruit oil was catalyzed by BrΦnsted acidic ionic liquid of 1-(4-sulfonic acid)butyl-pyridinium hydrosulfate. The ionic liquid was synthesized with acetone as solvent. The functions of ionic liquid catalyst dosage, mole ratio of methanol to Swida wilsoniana oil, reaction temperature and reaction time on process and ionic liquid properties were investigated. The transesterification characteristics were improved by that ionic liquid. The optimal transesterification conditions were shown as n(methanol)/n (Swida wilsoniana oil) 12, m(catalyst)/m(Swida wilsoniana oil) 0.06, reaction temperature 160 °C and reaction time 6 h, transesterification rate reach 94.0%. The ionic liquid was stable, which can be reused more than six times. Main quality indexes of biodiesel prepared come up to the biodiesel standard of GB/T20828-2007 in China.\",\"PeriodicalId\":6427,\"journal\":{\"name\":\"2013 International Conference on Materials for Renewable Energy and Environment\",\"volume\":\"18 1\",\"pages\":\"355-359\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2013 International Conference on Materials for Renewable Energy and Environment\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICMREE.2013.6893682\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2013 International Conference on Materials for Renewable Energy and Environment","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICMREE.2013.6893682","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2

摘要

以1-(4-磺酸)丁基氢硫酸吡啶为酸性离子液体BrΦnsted为催化剂,研究了以枸橼油为原料制备生物柴油的工艺。以丙酮为溶剂合成离子液体。考察了离子液体催化剂用量、甲醇与油的摩尔比、反应温度和反应时间对反应过程和离子液体性能的影响。该离子液体改善了酯交换特性。最佳酯交换条件为n(甲醇)/n(槐油)12,m(催化剂)/m(槐油)0.06,反应温度160℃,反应时间6 h,酯交换率可达94.0%。离子液体稳定,可重复使用6次以上。制备的生物柴油主要质量指标达到中国GB/T20828-2007生物柴油标准。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Swida wilsoniana oil based biodiesel catalyzed by 1-(4-sulfonic acid) butyl-pyridinium hydrosulfate
In the present work, biodiesel feedstock from Swida wilsoniana fruit oil was catalyzed by BrΦnsted acidic ionic liquid of 1-(4-sulfonic acid)butyl-pyridinium hydrosulfate. The ionic liquid was synthesized with acetone as solvent. The functions of ionic liquid catalyst dosage, mole ratio of methanol to Swida wilsoniana oil, reaction temperature and reaction time on process and ionic liquid properties were investigated. The transesterification characteristics were improved by that ionic liquid. The optimal transesterification conditions were shown as n(methanol)/n (Swida wilsoniana oil) 12, m(catalyst)/m(Swida wilsoniana oil) 0.06, reaction temperature 160 °C and reaction time 6 h, transesterification rate reach 94.0%. The ionic liquid was stable, which can be reused more than six times. Main quality indexes of biodiesel prepared come up to the biodiesel standard of GB/T20828-2007 in China.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Analysis about the distributed energy supply system based on LCA Swida wilsoniana oil based biodiesel catalyzed by 1-(4-sulfonic acid) butyl-pyridinium hydrosulfate Preparation of the WO3/TiO2 using microwave-heating in ionic liquid and its application in electrocatalysis Wind power prediction with LSSVM model based on data stratification pretreatment A fast model to identify multiple indoor contaminant sources with known releasing time by considering real sensor characteristics
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1