具有低介电常数和非脆性破坏的陶瓷-陶瓷复合材料

D. Partlow
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引用次数: 6

摘要

采用硼铝硅酸盐纤维增强堇青石基基体,制备了具有低介电常数和非脆性破坏的复合材料。由于这些纤维在高温下复合固结过程中通常会受到氧化基的化学侵蚀,因此在复合材料制造之前,需要在纤维上应用屏障/脱粘涂层,以获得良好的复合性能。采用已知的方法涂覆氮化硼涂层,其中纤维内的B{sub 2}O{sub 3}扩散到表面并被氮化。纤维拉伸试验表明,涂层工艺对纤维强度没有明显降低,涂层工艺制备的复合材料力学性能优于化学气相沉积阻挡层涂层为BN或碳的复合材料。
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A ceramic-ceramic composite with low dielectric constant and nonbrittle failure
A composite having low dielectric constant and displaying nonbrittle failure was prepared using a cordierite-based matrix reinforced with boron aluminosilicate fibers. Since these fibers are normally chemically attacked by an oxide matrix during composite consolidation at high temperatures, good composite behavior required the application of a barrier/debonding coating on the fibers prior to composite fabrication. A boron nitride coating was applied using a known process, in which B{sub 2}O{sub 3} within the fiber diffuses to the surface and is nitrided. Fiber tensile testing showed that the coating process did not significantly lower the fiber strength, and the composite prepared with fibers coated by this process showed better mechanical properties than composites in which the barrier coating was either BN or carbon applied by chemical vapor deposition.
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