{"title":"熔融电解质的高温振动光谱","authors":"M. M. Gafurov, K. Rabadanov","doi":"10.1080/05704928.2022.2048305","DOIUrl":null,"url":null,"abstract":"Abstract Spectroscopic studies of molten electrolytes have been carried out for more than 50 years. The information available in the literature on the problems arising in high-temperature spectroscopic measurements of molten electrolytes, as well as methods and technical solutions to overcome them, and the design of optical heating cells used for these purposes is fragmentary. The purpose of this review is to summarize the information available in the literature on techniques and methods for high-temperature spectroscopic measurements of molten electrolytes. A description of various techniques used in spectroscopic studies of molten electrolytes, including IR transmission spectroscopy, reflection and emission spectroscopy, reflection-adsorption spectroscopy, spectroelectrochemical Raman and IR spectroscopy is presented. A description of the design of the corresponding optical heating cells is given, as well as examples of spectra obtained using them. The review is useful for researchers studying electrolyte melts and specialists developing medium-temperature chemical current sources based on them. GRAPHICAL ABSTRACT","PeriodicalId":8100,"journal":{"name":"Applied Spectroscopy Reviews","volume":"86 1","pages":"489 - 508"},"PeriodicalIF":5.4000,"publicationDate":"2022-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"High-temperature vibrational spectroscopy of molten electrolytes\",\"authors\":\"M. M. Gafurov, K. Rabadanov\",\"doi\":\"10.1080/05704928.2022.2048305\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Spectroscopic studies of molten electrolytes have been carried out for more than 50 years. The information available in the literature on the problems arising in high-temperature spectroscopic measurements of molten electrolytes, as well as methods and technical solutions to overcome them, and the design of optical heating cells used for these purposes is fragmentary. The purpose of this review is to summarize the information available in the literature on techniques and methods for high-temperature spectroscopic measurements of molten electrolytes. A description of various techniques used in spectroscopic studies of molten electrolytes, including IR transmission spectroscopy, reflection and emission spectroscopy, reflection-adsorption spectroscopy, spectroelectrochemical Raman and IR spectroscopy is presented. A description of the design of the corresponding optical heating cells is given, as well as examples of spectra obtained using them. The review is useful for researchers studying electrolyte melts and specialists developing medium-temperature chemical current sources based on them. GRAPHICAL ABSTRACT\",\"PeriodicalId\":8100,\"journal\":{\"name\":\"Applied Spectroscopy Reviews\",\"volume\":\"86 1\",\"pages\":\"489 - 508\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2022-03-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Spectroscopy Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/05704928.2022.2048305\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"INSTRUMENTS & INSTRUMENTATION\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Spectroscopy Reviews","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/05704928.2022.2048305","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"INSTRUMENTS & INSTRUMENTATION","Score":null,"Total":0}
High-temperature vibrational spectroscopy of molten electrolytes
Abstract Spectroscopic studies of molten electrolytes have been carried out for more than 50 years. The information available in the literature on the problems arising in high-temperature spectroscopic measurements of molten electrolytes, as well as methods and technical solutions to overcome them, and the design of optical heating cells used for these purposes is fragmentary. The purpose of this review is to summarize the information available in the literature on techniques and methods for high-temperature spectroscopic measurements of molten electrolytes. A description of various techniques used in spectroscopic studies of molten electrolytes, including IR transmission spectroscopy, reflection and emission spectroscopy, reflection-adsorption spectroscopy, spectroelectrochemical Raman and IR spectroscopy is presented. A description of the design of the corresponding optical heating cells is given, as well as examples of spectra obtained using them. The review is useful for researchers studying electrolyte melts and specialists developing medium-temperature chemical current sources based on them. GRAPHICAL ABSTRACT
期刊介绍：
Applied Spectroscopy Reviews provides the latest information on the principles, methods, and applications of all the diverse branches of spectroscopy, from X-ray, infrared, Raman, atomic absorption, and ESR to microwave, mass, NQR, NMR, and ICP. This international, single-source journal presents discussions that relate physical concepts to chemical applications for chemists, physicists, and other scientists using spectroscopic techniques.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
