用于SERS应用的花状纳米银的合成

Christa Desmonda, Y. Tai
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摘要

表面增强拉曼散射(SERS)是一种高灵敏度检测吸附在金属表面的分子的光谱分析技术,主要是Ag、Au和Cu。表面增强可使强度增加106倍以上。一般来说,SERS有两种机制:化学增强和电磁增强。化学增强来自于吸附分子与金属表面的相互作用,而电磁增强来自于10-200 nm范围内纳米级表面粗糙度的表面等离激元共振。最大的SERS增强通常出现在聚集的金属纳米颗粒之间表面粗糙度对增强SERS效果也起着重要作用。Hongyan等人成功地合成了表面高度粗化的花状银颗粒,其尺寸从500 nm到2 μ m
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Synthesis of flower-like silver nanoparticles for SERS application
Surface-enhanced Raman scattering (SERS) is an optical spectroscopic analysis techniques for the highly sensitive detection of molecules adsorbed on metal surfaces, mainly Ag, Au, and Cu. Surface enhancement can yield the increasing in intensity more than a factor of 106. [1] In general, there are two mechanisms involve in SERS: chemical enhancement and electromagnetic enhancement. Chemical enhancement is come from the interaction between adsorbed molecules and the metal surface, while electromagnetic enhancement due to the surface plasmon resonance of nanoscale surface roughness in the 10–200 nm range. The largest SERS enhancement are often present in between aggregated metal nanoparticles.[2] Surface roughness also play an important role on giving enhancement of SERS effect. Hongyan, et al have been succeeded synthesis highly surface-roughened flower-like silver particles with sizes from 500 nm to 2 µm.[3]
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