N80碳钢在酸性NaCl溶液中的缝隙腐蚀行为:O2的影响

Yizhou Li, Jie Mu, Zhongyu Cui, Xin Wang
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引用次数: 3

摘要

研究了氧对N80碳钢在酸性NaCl溶液中缝隙腐蚀的影响。在酸性NaCl溶液中,有氧或无氧均可引起N80碳钢的缝隙腐蚀。裂缝腐蚀后,在裂缝口附近可形成较深的腐蚀槽。N80碳钢的缝隙腐蚀主要是由于在酸性NaCl溶液中,缝隙内pH值升高所致。溶液中O2的存在对缝隙外的阴极反应过程有促进作用,但对缝隙内的阴极反应过程没有促进作用。O2可增强内外钢之间的电偶腐蚀作用,进而促进缝隙腐蚀。
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The crevice corrosion behavior of N80 carbon steel in acidic NaCl solution: The effect of O2
The effect of O2 on crevice corrosion of N80 carbon steel in acidic NaCl solution is investigated. Crevice corrosion of N80 carbon steel could be initiated with or without O2 in acidic NaCl solution. A deep corrosion groove could be formed near the crevice mouth after crevice corrosion. The crevice corrosion of N80 carbon steel is ascribed to the increased pH inside the crevice in acidic NaCl solution. The presence of O2 in the solution could enhance the cathodic reaction processes outside the crevice, but it is not significant for the cathodic reaction processes inside the crevice. The galvanic corrosion effect between inner and outer steels could be enhanced by O2 and then promote crevice corrosion.
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