(U,Nd)O2的表面表征:三价掺杂剂对UO2结构的影响

Jeongmook Lee, Jandee Kim, Young‐Sang Youn, Jong‐Yun Kim, S. Lim
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引用次数: 4

摘要

利用拉曼光谱对(U,Nd)O2球团的表面结构进行了表征,研究了三价掺杂对UO2表面晶格的影响。通过分析x射线衍射谱计算的晶格参数,确定了每个样品颗粒的化学计量。样品的拉曼光谱显示了与氧空位有关的缺陷结构。(U,Nd)O2球团中氧空位的浓度受Nd掺杂水平的影响。
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Surface characterization of (U,Nd)O2: the influence of trivalent-dopant on structure of UO2
The surface structures of (U,Nd)O2 pellets were characterized by using Raman spectroscopy to study the influence of trivalent-dopant on a UO2 surface lattice. The stoichiometry of each sample pellet was confirmed by analyzing the lattice parameter calculated from X-ray diffraction spectra. Raman spectra of the sample pellets showed the defect structures related to oxygen vacancies. The concentration of oxygen vacancies in (U,Nd)O2 pellets is affected by the Nd doping level.
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