化学镀镍作为抗结垢合金在热生产中的应用

Da Zhu, L. Gong, Xiaoyong Qiu, Wenjihao Hu, Jun Huang, Ling Zhang, Vahidoddin Fattahpour, Mahdi Mahmoudi, Jingli Luo, Hongbo Zeng
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引用次数: 1

摘要

结垢是热采作业中的一个主要问题,例如蒸汽辅助重力泄油(SAGD)作业。除了提供良好的腐蚀环境外,结垢还可能导致防砂装置严重堵塞。因此,用于热采设备和完井的任何涂层都应具有显著的抗结垢表面性能。本文对化学镀镍(EN-coating)在热工环境中的应用进行了详细的研究,包括现场和实验室测试。最初,在实验室对涂覆和未涂覆的碳钢样品进行测试,以评估无机和有机材料的结垢、硬度和附着力。成功的实验室测试会导致现场测试计划,其中包括将en涂层和未涂层样品下入水平井进行热采。样品在一定时间后回收,用x射线光电子能谱(XPS)和能量色散能谱(EDS)综合分析涂层和未涂层碳钢上污垢物质的积累情况。本研究建议应用en涂层技术来解决热生产中有机和无机材料的结垢和粘附问题。综合实验室测试和SAGD井的现场数据表明,在恶劣的热采环境下,en涂层显著提高了油井的完整性。
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Application of Electroless Nickel Coating as a Scaling Resistant Alloy in Thermal Production
The scaling has been found to be a major problem in thermal production, such as in the Steam-Assisted Gravity Drainage (SAGD) operation. In addition to providing a favorite environment for corrosion, scaling could result in extreme plugging in sand control devices. Therefore, any coatings for the equipment and completion in thermal production should provide significant anti-scaling surface properties. This paper presents a detailed study, including field and laboratory testing, on application of the Electroless Nickel Coating (EN-coating) in thermal production environment. Initially, EN-coated and uncoated carbon steel samples were tested in laboratory to assess the scale, hardness and adhesion of inorganic and organic materials. Successful laboratory testing lead to a field testing plan, which involves deploying the EN-coated and uncoated samples into a horizontal well for thermal production. The specimens were recovered after certain time and a comprehensive X-ray Photoelectron Spectroscopy (XPS) and Energy-Dispersive Spectroscopy (EDS) were performed to assess accumulation of fouling substances on EN-coated and uncoated carbon steel. This study suggests the application of the EN-coating technology to solve the problems caused by scale, and adhesion of organic and inorganic material in thermal production. The comprehensive laboratory testing and field data from the SAGD wells shows that EN-coating significantly improves the well integrity in the harsh thermal production environment.
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