活化乳苹果果皮粉去除水溶液中孔雀石绿染料

Ashwini Kamath, N. R.
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引用次数: 0

摘要

采用马弗炉炭化的方法,对水果废弃物蛋黄苹果皮粉(CAPP)进行了活化处理,提高了其表面吸附能力,并将其作为吸附剂用于去除水中的孔雀石绿(MG)。生物吸附剂的炭化在高效吸附中起着关键作用,吸附前后的扫描电镜表面分析证明了这一点。考察了初始染料浓度(10-40ppm)、pH(3-7)、接触时间(15- 90min)和吸附剂用量(0.1-0.6 mg/50ml)等参数对CAPP脱色性能的影响。微酸性条件下吸附效果较好,pH为6时去除率最高。当接触时间为75 min,吸附剂用量为0.3mg/50ml时,去除率最高(91.5%),为95.3%。动力学研究表明,动力学数据符合拟一阶模型。等温线研究还表明,MG在CAPP上的吸附更符合Langmuir模型,而不是Freundlich模型。结果表明,CAPP是一种很有前途的去除水中和废水中MG的替代方法。
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Removal of malachite green dye in aqueous solution by Activated Custard apple (Annona Squamosa) Peel Powder
In the present study Custard apple peel powder (CAPP), a fruit waste, was activated by carbonizing in a Muffle Furnace to improve its surface adsorption capacity and used as an adsorbent for removal of Malachite Green (MG) from aqueous solution. Carbonisation of the bioadsorbent plays a key role in efficient adsorption which is proved by surface analysis of the bioadsorbent by Scanning Electron Microscope before and after adsorption. The color removal performance of CAPP has been investigated using parameters such as initial dye concentration (10-40ppm), pH (3-7), time of contact (15-90 min) and adsorbent dosage (0.1-0.6 mg/50ml). Adsorption was favorable at slightly acidic condition and the maximum removal was obtained at pH 6. Percentage of dye removal was maximum when the contact time was 75 min(91.5%) and adsorbent dosage of 0.3mg/50ml (95.3%). The kinetic studies revealed that the kinetic data fitted well to the pseudo‐first‐order model. The isotherm study also indicated that MG adsorption on CAPP matched well with the Langmuir model rather than the Freundlich model. The results show that CAPP can be a promising alternate for the removal of MG from aqueous solutions and effluents.
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