溶胶-凝胶法制备纯氧化锌和掺杂铟氧化锌纳米粒子的结构和形态特征

M. Poloju, M. V. Ramana Reddy
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引用次数: 2

摘要

采用简单的溶胶-凝胶法制备了高纯氧化锌纳米颗粒和掺杂铟氧化锌纳米颗粒,温度为70℃。采用低成本溶胶-凝胶法制备了Zn1-xInxO (x=0.01 ~ 0.08原子百分比)掺杂铟(In)的氧化锌。用XRD对粉末进行了结构分析。从衍射数据发现,纯粉和掺铟粉均形成了单相六方纤锌矿晶体结构。计算了合金的应变、晶格常数、晶粒尺寸、位错密度、Zn和O之间的键长等微观组织参数。利用XRD和SEM计算得到的粒度值对结晶度指数进行了估算。通过观察所得纳米材料的结晶度指数,证实了材料具有多晶性。
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Structural and morphological features of sol-gel processed pure and Indium doped ZnO nanoparticles
High purity ZnO nano particles and Indium (In) doped Zinc oxide (ZnO) nano particles were synthesized by simple sol-gel technique at low temperature of 70°C. Different compositions of Indium (In) doped zinc oxide with Zn1-xInxO (x=0.01 to 0.08 atomic percent) were prepared by low cost sol-gel technique. The powders were examined for their structural study using XRD. It has been found from diffraction data that the pure and Indium doped powders have formed to be single phase hexagonal wurtzite crystal structure. The microcstrutured parameters such as strain, lattice constant, particle size, dislocation density, bond lengths between Zn and O were calculated. Using the calculated values of particle size from XRD & SEM crystallinity index was estimated. From the observed crystallinity index data of the prepared nano materials it was confirmed that the materials were showing polycrystalline nature.
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