杂芳烃化合物亲电取代的动力学和机理。第二十五章部分。一些2-氨基吡啶衍生物的酸催化氢交换

A. El-Anani, P. Jones, A. Katritzky
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引用次数: 4

摘要

报道了2-氨基-5-氯吡啶、5-氯-2-二甲氨基吡啶和2-氨基-5-溴吡啶1-氧化物在3位上的氢交换以及2-氨基-3-甲基吡啶在5位上的氢交换速率谱。
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The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XXV. The acid-catalysed hydrogen-exchange of some 2-aminopyridine derivatives
Rate profiles are reported for hydrogen exchange at the 3-position for 2-amino-5-chloropyridine, 5-chloro-2-dimethylaminopyridine, and 2-amino-5-bromopyridine 1-oxide and for exchange at the 5-position for 2-amino-3-methylpyridine.
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Kinetics and mechanism of electrophilic substitution of heteroaromatic compounds. Part XXIII. Acid-catalysed hydrogen exchange of quinoline, isoquinoline, and their N-oxides Dielectric relaxation and dipole moments of substituted pyrroles Free-radical addition to olefins. Part VII. Addition of trichloromethyl radicals to chloro-olefins Primary hydrogen isotope effects on the rate of ionization of nitroethane in mixtures of water and dimethyl sulphoxide The conformational analysis of saturated heterocycles. Part XXXV. 1-Phenoxymethyl-3,4-dihydroisoquinolines
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