{"title":"(K,Na)NbO - 3基压电陶瓷的光致变色诱导宏观极化开关","authors":"Haiqin Sun, Qiannan Jia, Yong Li, Qiwei Zhang, Xihong Hao","doi":"10.2139/ssrn.3474465","DOIUrl":null,"url":null,"abstract":"The intriguing coupling interactions between photochromism and ferroelectric polarization were firstly observed in Sm doped (K<sub>0.5</sub>Na<sub>0.5</sub>)NbO<sub>3</sub> piezoceramics. After 407 nm irradiation, the maximum polarization (P<sub>max</sub>) and remanent polarization (Pr) intensities were dramatically decreased, whereas the coercive field, leakage current and photocurrent showed the remarkable increase. The variations of the polarization and photocurrent can be reversibly converted by alternating light irradiation and thermal stimulus, suggesting good polarization switching performance. This work provides a new route to effectively modulate ferro-/piezoelectric and photocurrent properties of ferroelectric materials by the non-contact remote control of light.","PeriodicalId":9905,"journal":{"name":"ChemRN: Optical Materials (Topic)","volume":"19 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photochromism-Induced Macroscopic Polarization Switching in (K,Na)NbO 3-Based Piezoceramics\",\"authors\":\"Haiqin Sun, Qiannan Jia, Yong Li, Qiwei Zhang, Xihong Hao\",\"doi\":\"10.2139/ssrn.3474465\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The intriguing coupling interactions between photochromism and ferroelectric polarization were firstly observed in Sm doped (K<sub>0.5</sub>Na<sub>0.5</sub>)NbO<sub>3</sub> piezoceramics. After 407 nm irradiation, the maximum polarization (P<sub>max</sub>) and remanent polarization (Pr) intensities were dramatically decreased, whereas the coercive field, leakage current and photocurrent showed the remarkable increase. The variations of the polarization and photocurrent can be reversibly converted by alternating light irradiation and thermal stimulus, suggesting good polarization switching performance. This work provides a new route to effectively modulate ferro-/piezoelectric and photocurrent properties of ferroelectric materials by the non-contact remote control of light.\",\"PeriodicalId\":9905,\"journal\":{\"name\":\"ChemRN: Optical Materials (Topic)\",\"volume\":\"19 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemRN: Optical Materials (Topic)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3474465\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemRN: Optical Materials (Topic)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3474465","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photochromism-Induced Macroscopic Polarization Switching in (K,Na)NbO 3-Based Piezoceramics
The intriguing coupling interactions between photochromism and ferroelectric polarization were firstly observed in Sm doped (K0.5Na0.5)NbO3 piezoceramics. After 407 nm irradiation, the maximum polarization (Pmax) and remanent polarization (Pr) intensities were dramatically decreased, whereas the coercive field, leakage current and photocurrent showed the remarkable increase. The variations of the polarization and photocurrent can be reversibly converted by alternating light irradiation and thermal stimulus, suggesting good polarization switching performance. This work provides a new route to effectively modulate ferro-/piezoelectric and photocurrent properties of ferroelectric materials by the non-contact remote control of light.
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