FTIR光谱法在水流分析中的检测原理

R. Schindler, B. Lendl
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引用次数: 17

摘要

而FTIR光谱检测通常用于气相色谱(B. Erikson, Anal。化学。, 1998,70,801a),但它在液相色谱(LC)和流动注射分析(FIA)中的应用是一个相当奇特的例外。最突出的原因是对大多数常见溶剂,尤其是水有较强的红外吸收性。因此,FTIR光谱通常甚至不被认为是一种有价值的检测方法。这种做法忽略了FTIR光谱提供了一些独特的特征,现在使用现代仪器,可以以有利的方式加以利用。这篇重点文章的目的是演示LC和FIA中广泛的可能应用。认为FTIR光谱学过于新奇而不适合常规使用可能是一种奢侈,因为它忽视了一种简单的分析方法。术语流动分析(FA)将用于为LC和FIA提供一个共同的掩护,因为两者都依赖于将样品注入流动的流中,通过调制器并记录瞬态峰值。虽然在调制器中发生的过程是不同的,是FIA中的化学反应和LC中的分离,但相同的界面可以用于FTIR光谱仪作为检测器。所使用的界面可分为两类,一种是直接探测液体的流过细胞,另一种是在检测之前将分析物从载体液体中分离出来的溶剂去除界面。有必要强调这些技术的互补性(D. E. Pivonka和K. M. Kirkland, apple)。Spectrosc。, 1997,51,866),本重点将强调其特定的长处和弱点。由于水相系统在生物系统中具有很高的重要性,因此特别关注水相系统。由于水无疑是红外检测中最具挑战性的溶剂,对于其他溶剂,可以期望所提出的方法具有相同甚至更好的性能。此外,将详细讨论FA-FTIR仪器的三个发展前景:复杂化学计量方法的日益普及,分析仪器的小型化和组合化学的应用。
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FTIR spectroscopy as detection principle in aqueous flow analysis
Whereas FTIR spectroscopic detection is routinely used in gas chromatography (B. Erikson, Anal. Chem., 1998, 70, 801A), its use for liquid chromatography (LC) and flow injection analysis (FIA) is a rather exotic exception. The most prominent reason is the strong IR absorption of most of the common solvents, especially water. Hence FTIR spectroscopy is normally not even considered a valuable detection method. This practice neglects that FTIR spectroscopy offers some unique features which now, using modern instrumentation, can be exploited in an advantageous manner. It is the aim of this Highlight article to demonstrate the wide range of possible applications in LC and FIA. To regard FTIR spectroscopy as too exotic for routine use may be a luxury paid for with the neglect of a simple analytical approach. The term flow analysis (FA) will be used to provide a common cover for both LC and FIA because both rely on the injection of a sample into a flowing stream, passage through a modulator and recording of transient peaks. Although the processes taking place in the modulator are different, being chemical reactions in FIA and separations in LC, the same interfaces can be used for a FTIR spectrometer as a detector. The interfaces used can be divided into two categories, flow through cells where the liquid is probed directly, and solvent removal interfaces where the analyte is separated from the carrier liquid prior to detection. It is necessary to emphasize the complementary nature of these techniques (D. E. Pivonka and K. M. Kirkland, Appl. Spectrosc., 1997, 51, 866) and this Highlight will stress their particular strengths and weaknesses. Special focus is laid on aqueous phase systems because of their high importance in biological systems. As water is certainly the most challenging solvent for IR detection, equal or even better performance of the presented approaches can be expected for other solvents. Additionally three developments will be discussed in detail with respect to their prospects for FA-FTIR instruments: the increasing availability of sophisticated chemometric methods, the miniaturization of analytical instruments and applicaton to combinatorial chemistry.
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