氧压对氧化锌烧结的影响

W. Komatsu, Y. Moriyoshi
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引用次数: 1

摘要

在750°和850°C的等温收缩率测试中,研究了氧压对氧化锌烧结性能的影响。在750℃氧气环境下,烧结性能与Po2 /5.4成正比(Po2>2.5×10-2torr),与Po2 /5.4成正比(Po2> 3×10-3torr)。结果表明,烧结过程受间隙锌离子扩散转移的控制。在较低的氧压下,烧结速率与压力无关。这一结果可以解释为两种不同机制的共同作用,即间隙锌离子的扩散转移和间隙锌与氧之间的晶格形成过程。
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The effect of oxygen pressure on sintering of zinc oxide
The effect of oxygen pressure on sintering of zinc oxide has been investigated by measuring isothermal shrinkage of compacts at 750° and 850°C. The sinterability was proportional to Po2-1/5.4 at 750°C in oxygen atomsphere (Po2>2.5×10-2torr) and to Po2-1/5.4 at 850°C in Po2>3×10-3torr. The result indicates that the sintering process is controlled by diffusional transfer of interstitial zinc ions. In the lower oxygen pressure, the sintering rate was independent of the pressure. This result was explained by the cooperation of two different mechanisms, i.e., diffusional transfer of interstitial zinc ions and lattice formation process between interstitial zinc and oxygen.
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