用于柔性能量收集和存储模块的丝网印刷过孔

M. Kujala, T. Kololuoma, J. Keskinen, D. Lupo, M. Mäntysalo, T. Kraft
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引用次数: 8

摘要

本案例研究评估了使用银微粒油墨在能量收集和存储模块中应用的高度柔性丝网印刷通孔。通过双面丝网印刷法和重复(循环)弯曲试验,对印刷过孔的制作和可靠性进行了评估。在125 μm厚的PET上,通过激光切割(50、100、150和200 μm的公称直径),然后填充,并通过丝网印刷同时连接到相邻的过孔。为了研究印刷通孔在单片能量模块中的应用,该通孔被用于制造柔性印刷超级电容器(水电解质和碳电极)。结果表明:低粘度银墨(DuPont 5064H)填充孔的效果不如高粘度银墨(Asahi LS411AW),随着孔尺寸的增大(直径≥150 μm),只有孔的侧壁被涂覆;相反,朝日银浆填充孔更彻底,并表现出100%的收率(1010孔;100 μm公称通径)采用两步直接丝网印刷方法。在3万次循环后,弯曲测试显示没有通过特定击穿的迹象。结果表明,这种通过填充工艺可能与卷对卷丝网印刷兼容,以实现多层印刷电子设备。
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Screen Printed Vias for a Flexible Energy Harvesting and Storage Module
This case study evaluates a highly flexible screen printed through-hole-via using silver microparticle inks for applications in energy harvesting and storage modules. The printed vias fabrication and reliability are evaluated by means of a double sided screen-printing method and repetitive (cyclic) bending tests. Vias, in 125 μm thick PET, were laser cut (50, 100, 150, and 200 μm nominal diameter) then filled, and simultaneously connected to adjacent vias, by screen printing. To investigate the use of the printed via in a monolithic energy module, the vias were used for the fabrication of a flexible printed supercapacitor (aqueous electrolyte and carbon electrode).The results indicate that the lower viscosity silver ink (DuPont 5064H) does not fill the via as effectively as the higher viscosity ink (Asahi LS411AW), and only the sidewall of the vias are coated as the via size increases (≥ 150 μm diameter). Conversely, the Asahi silver paste fills the via more thoroughly and exhibited a 100 % yield (1010 vias; 100 μm nominal via diameter) with the 2-step direct screen-printing method. The bending test showed no signs of via specific breakdown after 30 000 cycles. The results indicate that this via filling process is likely compatible with roll-to-roll screen printing to enable multi-layered printed electronics devices.
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