水热法固载lisr2 (PO4)3中锶的比较研究

Y. N. Vaidyanath, K. G. Ashamanjari, M. Mylarappa, M. Ramu, K. Mahesh, S. Prashantha, H. P. Nagaswarupa, N. Raghavendra
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引用次数: 1

摘要

本研究的主要目的是在中压、中温条件下,利用软水热法合成不同的sr2在LiSr2(PO4)3晶体中的固定物。粉末x射线衍射证实,合成的LiSr2(PO4)3材料具有很好的相纯度和菱形结构晶体。能量分散x射线(EDX)光谱分析表明,它们的元素组成与锶的元素组成具有良好的相关性。通过扫描电镜(SEM)观察,发现其微观结构质量良好,表面光滑,具有亚透明和亚玻璃光泽。FTIR研究确定了掺杂是否影响了键结构,并揭示了O-H分子的存在和合成材料的微小结构变化。温度与重量%损失随温度升高而减小的TGA图显示,磷酸锶锶具有热稳定性,因此可用于某些光电器件。研究了LiSr2(PO4)3的电导率随过渡金属阳离子性质的变化。阻抗测试表明,该材料具有较好的离子电导率。
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Comparative study of different immobilization of strontium inLiSr2(PO4)3 crystal through hydrothermal process
The main objective of the present study was to synthesis the different immobilization of Sr+2 in LiSr2(PO4)3crystals using soft hydrothermal method at moderate pressure and temperature conditions.The powder X-ray diffraction confirms that, the synthesized LiSr2(PO4)3material has very good phase purity and crystalline with rhombohedralstructure.The energy-disperse X-ray (EDX) spectroscopic analysis shows their elemental composition correlating well with that of the strontium.Observation through a Scanning Electron Microscope (SEM) shows that microstructures of good quality and exhibited smooth surface, sub transparent and sub vitreous lustre. The FTIR studies was used to determine whether the bond structures were affected from the doping or not and revealed that the presence of O-H molecules and minute structural variations of synthesized materials.The TGA graph, temperature vs. weight % loss decreases with increasing the temperature showsLithium strontium phosphateas thermally stable so it is used as some optoelectronic device applications.The electrical conductivity of LiSr2(PO4)3was investigated as a function of the nature of the transition-metal cation. Impedancemeasurementshow that the materials have relatively good ionic conductance.
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