汞锡体系组成的研究1

D. F. Taylor, C. L. Burns
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引用次数: 18

摘要

采用差热分析技术对汞锡体系的组成进行了研究;扩散和化学分析;和x射线衍射。汞-银-锡体系之所以引起人们的兴趣,是因为它是牙科汞合金的基础,而汞合金是最重要的单一牙科修复材料。对于三元体系和汞锡二元体系,关于这些合金的构成的信息是不完整的。本研究致力于汞锡体系的研究,作为三元合金研究的先决条件。各种方法得到的结果并不完全一致。它们表明该系统比以前报道的更为复杂。普里瑟里希(Prytherich)报告的β相的其他证据被发现,但其组成极限和共析温度仍有待证实。发现伽马相组成极限与先前的值不同。通过x射线衍射发现了盖勒δ相的确证数据和以前未报道的ε相的可能证据。热分析结果表明可能存在其他方法未证实的附加相。在此基础上提出了一种改进的汞锡相图。
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An Investigation of the Constitution of the Mercury-Tin System1
An investigation of the constitution of the mercury-tin system was made by a combination of three techniques: differential thermal analysis; diffusion and chemical analysis; and X-ray diffraction. The mercury-silver-tin system is of interest because it is the basis of dental amalgam, the most important single dental restorative material. Information as to the constitution of these alloys is incomplete for both the ternary system and the mercury-tin binary system. This study was devoted to the investigation of the mercury-tin system as a prerequisite to a study of the ternary alloys. The results obtained by the various methods are not in complete agreement. They indicate that the system is more complex than previously reported. Additional evidence for the beta phase as reported by Prytherich was found but the composition limits and eutectoid temperature remain to be confirmed. The gamma phase composition limits were found to differ from earlier values. Corroborative data for Gayler’s delta phase and possible evidence for a previously unreported epsilon phase have been found by X-ray diffraction. The thermal analysis results indicate the possible existence of additional phases unconfirmed by other methods. A modified mercury-tin phase diagram based upon these findings is proposed.
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