TiO2光催化降解处理油页岩干馏废水的研究

Shujiang Wang, Xun Dai, Yanyan Sun
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引用次数: 1

摘要

由于油页岩的精馏工艺独特,产生的废水中含有大量的油类、硫化物、氰化物、挥发性酚、氨等有毒物质,其COD含量高且耐火物质多。本文试图建立一种综合的油页岩二氧化钛光催化水处理方法,并对催化污水处理因素如反应时间、催化剂类型、催化剂体积、强度、温度等进行了详细的研究。建立了一系列能有效、准确地检测废水中污染物含量的方法,同时也能检测油页岩干馏废水等因素;作为全面解决油页岩蒸馏废水的基础。采用溶胶-凝胶法制备了TiO2。分析了TiO2光催化降解油页岩炭化废水的机理。同时,对油页岩炭化废水及其影响因素进行了研究。
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Study on the treatment of wastewater of oil shale retorting by photocatalytic degradation with TiO2
As the oil shale retorting process is unique, resulting wastewater contains large amounts of oil, sulfide, cyanide, volatile phenol, ammonia and other toxic substances, its high content of COD and refractory material and more. This paper attempts to establish a comprehensive titanium dioxide photocatalytic water treatment methods of oil shale, and shadow detail catalytic sewage treatment factors such as reaction time, catalyst type, catalyst volume, intensity, temperature, etc. We establish a series of methods which can effectively and precisely test the pollutant content in waste water at the same time, but also of the oil shale retorting wastewater and other factors; as a total solution to wastewater from oil shale retorting basis. TiO2 have been prepared by sol-gel processing. The mechanism of photocatalytic degradation with TiO2 used for treating carbonization wastewater of oil shale is analyzed. At the same time, carbonization wastewater of oil shale and other factors efflunced the results are also studied.
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